In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Ynamides are unique alkynes with a carbon–carbon triple bond directly attached to the
nitrogen atom bearing an electron-withdrawing group. The alkyne is strongly polarized by …

Allylation reactions are one of the most fundamental and productive C− C bond-forming
transformations, as the allyl group can provide a useful handle for further manipulation …

Abstract 6π electrocyclization has attracted interest in organic synthesis because of its high
stereospecificity and atom economy in the construction of versatile 5–7‐membered cycles …

We have achieved a sequential hydride-shift-triggered double C (sp3)–H bond
functionalization at a position adjacent to an oxygen atom and a benzylic/aliphatic position …

Herein, we disclose an efficient zinc-catalyzed formal [3+ 2] annulation of isoxazoles with
ynol ethers under exceptionally mild reaction conditions, leading to the atom-economical …

Straightforward synthesis of benzosiloles was achieved by the invention of Pd/acid-
catalyzed intramolecular anti-hydroarylation of aryloxyethynyl (aryl) silanes via ortho-C–H …

The regioselective transformation of alkynes represents a highly efficient bond-forming
strategy in organic synthesis. However, the enantiocontrol in the conversion of alkynes …

Alkynes, alkenes, and thiophenes are found to behave as a directing group for C–H bond
activation by a transition-metal catalyst. This collaborative interaction led to the discovery of …

An intramolecular exo‐hydroarylation of 2‐aryloxy‐1, 4‐disilylbut‐1‐en‐3‐ynes via ortho‐
C− H bond activation under palladium (0) and acid catalysis was found to give 2, 3‐bis …