N,O-Chelating Four-Membered Metallacyclic Titanium(IV) Complexes for Atom-Economic Catalytic Reactions
SA Ryken, LL Schafer - Accounts of Chemical Research, 2015 - ACS Publications
Conspectus Titanium, as the second most abundant transition metal in the earth's crust,
lends itself as a sustainable and inexpensive resource in catalysis. Its nontoxicity and …
lends itself as a sustainable and inexpensive resource in catalysis. Its nontoxicity and …
[HTML][HTML] 1, 3-N, O-Complexes of late transition metals. Ligands with flexible bonding modes and reaction profiles
1, 3-N, O-Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral
amino acids in metalloproteins. These structural units also display diverse coordination …
amino acids in metalloproteins. These structural units also display diverse coordination …
Capturing HBCy2: Using N,O‐Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration
N, O‐chelated complexes of RhI and IrI cooperatively and reversibly stabilized the B− H
bond of HBCy2 to afford six‐membered metallaheterocycles (M= Rh (7) or Ir (8)) having a δ …
bond of HBCy2 to afford six‐membered metallaheterocycles (M= Rh (7) or Ir (8)) having a δ …
Oxidation State Dependent Coordination Modes: Accessing an Amidate‐Supported Nickel (I) δ‐bis (C− H) Agostic Complex
Amidate‐supported two‐and three‐coordinate NiI complexes were synthesized by reduction
of the corresponding NiII precursors. A dramatic change in binding mode is observed upon …
of the corresponding NiII precursors. A dramatic change in binding mode is observed upon …
Disproportionation reactions of an organometallic Ni (I) amidate complex: scope and mechanistic investigations
DD Beattie, G Lascoumettes, P Kennepohl… - …, 2018 - ACS Publications
The N-heterocyclic carbene supported three-coordinate Ni (I) complex (IPr) Ni (κ1-NN (i Pr)
C (O) t Bu)(CNXyl)([2-CNXyl]; CNXyl= 2, 6-dimethylphenyl isocyanide) undergoes …
C (O) t Bu)(CNXyl)([2-CNXyl]; CNXyl= 2, 6-dimethylphenyl isocyanide) undergoes …
Phosphoramidate‐Supported Cp*IrIII Aminoborane H2B=NR2 Complexes: Synthesis, Structure, and Solution Dynamics
Reaction of aminoboranes H2B= NR2 (R= iPr or Cy) with the cationic Cp* IrIII
phosphoramidate complex [IrCp*{κ2‐N, O‐Xyl (N) P (O)(OEt) 2}][BArF4] generates the …
phosphoramidate complex [IrCp*{κ2‐N, O‐Xyl (N) P (O)(OEt) 2}][BArF4] generates the …
Reactivity of an Unsaturated Iridium(III) Phosphoramidate Complex, [Cp*Ir{κ2-N,O}][BArF4]
The three-legged piano stool complex [Cp* Ir (κ2-N, O-Xyl (N) P (O)(OEt) 2)(Cl)],[1](Cp*= η5-
C5Me5, Xyl= 2, 6-dimethylphenyl), was prepared from reaction of 0.5 equiv of [Cp* IrCl2] 2 …
C5Me5, Xyl= 2, 6-dimethylphenyl), was prepared from reaction of 0.5 equiv of [Cp* IrCl2] 2 …
Bis(tert-butylimido)bis(N,O-chelate)tungsten(VI) Complexes: Probing Amidate and Pyridonate Hemilability
JM Clarkson, LL Schafer - Inorganic Chemistry, 2017 - ACS Publications
Four new bis (tert-butylimido) bis (N, O-chelate) tungsten (VI) complexes (3–6), in which the
N, O-chelate is an amidate or pyridonate ligand, have been synthesized and characterized …
N, O-chelate is an amidate or pyridonate ligand, have been synthesized and characterized …
RhCl (PPh 3) 3-mediated C–H oxyfunctionalization of pyrrolido-functionalized bisazoaromatic pincers: a combined experimental and theoretical scrutiny of redox …
T Ghorui, S Roy, S Pramanik, K Pramanik - Dalton Transactions, 2016 - pubs.rsc.org
A potentially symmetrical NNN pyrrolido-functionalized pincer ligand, HL= 2, 5-bis
(phenylazo)-1H-pyrrole, reacts with [RhICl (PPh3) 3] in toluene in the presence of air …
(phenylazo)-1H-pyrrole, reacts with [RhICl (PPh3) 3] in toluene in the presence of air …
Synthesis and characterization of bridged bis (amidato) rare earth metal amides and their applications in C–N bond formation reactions
B Zhao, Y Xiao, D Yuan, C Lu, Y Yao - Dalton Transactions, 2016 - pubs.rsc.org
Based on three bisamide proligands H2Ln (n= 1–3)(H2L1=[(Me3C6H2CONHCH2) 2CH2],
H2L2=[(Me3C6H2CONHCH2) 2C (CH3) 2], H2L3=[Me3C6H2CONH (CH2) 2] 2NCH3) …
H2L2=[(Me3C6H2CONHCH2) 2C (CH3) 2], H2L3=[Me3C6H2CONH (CH2) 2] 2NCH3) …