Catalytic dehydrogenation of alcohols represents an attractive approach for future
applications as hydrogen storage systems and clean synthesis of fine chemicals. Herein, an …

Roles of the hydrogen atoms attached to the metal center of transition metal polyhydride
complexes, LnMHx (x≥ 3), are analyzed for about forty types of organic reactions catalyzed …

TiO2 is an effective and extensively employed photocatalyst, but its practical use in visible-
light-mediated organic synthesis is mainly hindered by its wide band gap energy. Herein, we …

An efficient synthesis of quinolines, pyrimidines, quinoxalines, pyrroles, and
aminomethylated aromatic compounds catalyzed by a well-defined Re (I) PNP pincer …

The reaction of the hexahydride OsH6 (PiPr3) 2 with a P, Ge, P-germylene-diphosphine
affords an osmium tetrahydride derivative bearing a Ge, P-chelate, which arises from the …

Potassium tert‐butoxide‐promoted acceptorless dehydrogenation of N‐heterocycles was
efficiently realized for the generation of N‐heteroarenes and hydrogen gas under transition …

The new energy supply systems' demand worldwide has increased significantly with the
development of mobile applications. An effective strategy for hydrogen supply offer a great …

The preparation of the hydroxo-osmium (IV) complex OsH3 (OH){xant (P i Pr2) 2}(xant (P i
Pr2) 2= 9, 9-dimethyl-4, 5-bis (diisopropylphosphino) xanthene) and its catalytic efficiency …

Two types of non-phosphine based manganese (I) complexes, NN-manganese carbonyl
complexes (Mn1–Mn5) and NNN/S-pincer complexes (Mn6–Mn10), have been assessed as …

Abstract A Mn (OAc) 3⋅ 2H2O‐catalyzed aerobic dehydrogenation of five and six‐
membered N‐heterocycles for the synthesis of N‐heteroarenes is reported. Of note, this …