The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

As a structural analog of oxazoline, imidazoline (4, 5‐dihydroimidazole) has received much
attention in the rational design of chiral ligands. The additional N‐substituent provides …

Get selective! Enantioselective allylation of ketimines derived from isatins by using chiral 1, 3‐
bis (imidazolin‐2‐yl) benzene (Phebim)–PdII complexes afforded products with good …

In this work, macro cyclic amine type of functional monomers,(4-vinylbenzyl)-1, 4, 7-
triazacyclononane (VBTN) and 1, 4-bishydroxyethyl-7-(4-vinylbenzyl)-1, 4, 7 …

Enantiomerically pure benzylic amines are important for the development of new drugs. A
readily accessible planar‐chiral ferrocene‐derived palladacycle is shown to be a highly …

This Review summarizes the advances in the catalytic enantioselective mono‐and
difunctionalization of alkenes, highlighting the fundamental role of ligands. Several types of …

Isoxazolinones constitute a class of heterocycles utilized for the development of novel drug
candidates. The cyclic oxime ester motif is also synthetically useful as it contains functional …

Conspectus Allylic amides, amines, and esters are key synthetic building blocks. Their
enantioselective syntheses under mild conditions is a continuing pursuit of organic synthesis …

Simple starting materials, high‐value products: A dinuclear ferrocene‐based PdII complex
transforms mixtures of racemic N‐benzoyl α‐amino acids, nitroolefins, acetic anhydride, and …

Conclusions Chiral ferrocene derivatives continue to serve as prominent catalyst class for a
number of important reactions. Apart from asymmetric hydrogenations, which are broad topic …