A review on anion-pillared metal–organic frameworks (APMOFs) and their composites with the balance of adsorption capacity and separation selectivity for efficient …

X Li, H Bian, W Huang, B Yan, X Wang, B Zhu - Coordination Chemistry …, 2022 - Elsevier
Metal-organic frameworks (MOFs) have gained widespread attention in many fields,
especially in gas adsorption and separation. However, traditional MOFs always suffer from a …

Advances in adsorptive separation of benzene and cyclohexane by metal-organic framework adsorbents

S Mukherjee, D Sensharma, OT Qazvini, S Dutta… - Coordination Chemistry …, 2021 - Elsevier
The chemical industry represents ca. 7% of the global GDP and 40% of its immense energy
footprint stems from the separation/purification processes of commodity chemicals …

Fine pore engineering in a series of isoreticular metal-organic frameworks for efficient C2H2/CO2 separation

J Wang, Y Zhang, Y Su, X Liu, P Zhang, RB Lin… - Nature …, 2022 - nature.com
The separation of C2H2/CO2 is not only industrially important for acetylene purification but
also scientifically challenging owing to their high similarities in physical properties and …

Programmed fluorine binding engineering in anion-pillared metal-organic framework for record trace acetylene capture from ethylene

XW Gu, E Wu, JX Wang, HM Wen, B Chen, B Li… - Science …, 2023 - science.org
Porous physisorbents are attractive candidates for selective capture of trace gas or volatile
compounds due to their low energy footprints. However, many physisorbents suffer from …

Incorporation of multiple supramolecular binding sites into a robust MOF for benchmark one-step ethylene purification

E Wu, XW Gu, D Liu, X Zhang, H Wu, W Zhou… - Nature …, 2023 - nature.com
One-step adsorption separation of C2H4 from ternary C2 hydrocarbon mixtures remains an
important and challenging goal for petrochemical industry. Current physisorbents either …

Interlayer Symmetry Control in Flexible-Robust Layered Metal–Organic Frameworks for Highly Efficient C2H2/CO2 Separation

F Zheng, R Chen, Z Ding, Y Liu, Z Zhang… - Journal of the …, 2023 - ACS Publications
Removal of the CO2 impurities from C2H2/CO2 mixtures is an essential process to produce
high-purity C2H2. Fabricating an adsorbent capable of discriminating these species, which …

An Ultramicroporous Hydrogen‐Bonded Organic Framework Exhibiting High C2H2/CO2 Separation

Y Yang, H Zhang, Z Yuan, JQ Wang… - Angewandte …, 2022 - Wiley Online Library
The separation of C2H2/CO2 is not only industrially important for acetylene purification but
also great scientific challenge due to their very similar molecular size and physical …

Synergistic binding sites in a hybrid ultramicroporous material for one-step ethylene purification from ternary C2 hydrocarbon mixtures

P Zhang, Y Zhong, Y Zhang, Z Zhu, Y Liu, Y Su… - Science …, 2022 - science.org
One-step separation of C2H4 from ternary C2H2/C2H4/C2H6 hydrocarbon mixtures is of
great significance in the industry but is challenging due to the similar sizes and physical …

Vertex Strategy in Layered 2D MOFs: Simultaneous Improvement of Thermodynamics and Kinetics for Record C2H2/CO2 Separation Performance

X Zhu, T Ke, J Zhou, Y Song, Q Xu… - Journal of the …, 2023 - ACS Publications
Developing adsorbents with multiple merits in capacity, selectivity, mass transfer, and
stability toward C2H2/CO2 separation is crucial and challenging for producing high-purity …

Construction of Negative Electrostatic Pore Environments in a Scalable, Stable and Low‐Cost Metal‐organic Framework for One‐Step Ethylene Purification from …

HM Wen, C Yu, M Liu, C Lin, B Zhao, H Wu… - Angewandte …, 2023 - Wiley Online Library
One‐step separation of C2H4 from ternary C2 mixtures by physisorbents remains a
challenge to combine excellent separation performance with high stability, low cost, and …