Aldehyde N,N‐Dialkylhydrazones as Neutral Acyl Anion Equivalents: Umpolung of the Imine Reactivity
R Brehme, D Enders, R Fernandez… - European Journal of …, 2007 - Wiley Online Library
The isoelectronic replacement of the α‐carbon of enamines by nitrogen leads to the
corresponding hydrazones, and thus, they can be termed “aza‐enamines”. Hence, aldehyde …
corresponding hydrazones, and thus, they can be termed “aza‐enamines”. Hence, aldehyde …
Asymmetric Formal Carbonyl-Ene Reactions of Formaldehyde tert-Butyl Hydrazone with α-Keto Esters: Dual Activation by Bis-urea Catalysts
A Crespo-Peña, D Monge… - Journal of the …, 2012 - ACS Publications
The dual activation of α-keto esters and formaldehyde tert-butyl hydrazone by BINAM-
derived bis-ureas is the key to achieve high reactivity and excellent enantioselectivities in …
derived bis-ureas is the key to achieve high reactivity and excellent enantioselectivities in …
Organocatalytic nucleophilic addition of hydrazones to imines: synthesis of enantioenriched vicinal diamines
Y Wang, Q Wang, J Zhu - Angewandte Chemie International …, 2017 - Wiley Online Library
In the presence of a catalytic amount of chiral phosphoric acid, nucleophilic addition of N‐
monosubstituted hydrazones to N‐Boc imines affords differentially protected vicinal …
monosubstituted hydrazones to N‐Boc imines affords differentially protected vicinal …
Reaction of dicarbonates with carboxylic acids catalyzed by weak Lewis acids: general method for the synthesis of anhydrides and esters
G Bartoli, M Bosco, A Carlone, R Dalpozzo… - …, 2007 - thieme-connect.com
The reaction between carboxylic acids (RCOOH) and dialkyl dicarbonates [(R 1 OCO) 2 O],
in the presence of a weak Lewis acid such as magnesium chloride and the corresponding …
in the presence of a weak Lewis acid such as magnesium chloride and the corresponding …
Formaldehyde tert-butyl hydrazone as a formyl anion equivalent: asymmetric addition to carbonyl compounds
The asymmetric 1, 2-addition of formyl anion equivalents to carbonyl compounds is a
powerful synthetic tool that ideally provide access to highly functionalizable α-hydroxy …
powerful synthetic tool that ideally provide access to highly functionalizable α-hydroxy …
A mild and efficient procedure for ring-opening reactions of piperidine and pyrrolidine derivatives by single electron transfer photooxidation
G Cocquet, C Ferroud, A Guy - Tetrahedron, 2000 - Elsevier
A Mild and Efficient Procedure for Ring-Opening Reactions of Piperidine and Pyrrolidine Derivatives
by Single Electron Transfer Photooxidation - ScienceDirect Skip to main contentSkip to article …
by Single Electron Transfer Photooxidation - ScienceDirect Skip to main contentSkip to article …
Computer-assisted mechanistic evaluation of organic reactions. 20. Ene and retro-ene chemistry
GD Paderes, WL Jorgensen - The Journal of Organic Chemistry, 1992 - ACS Publications
The pericyclic module of the computer program cameo has been expanded to encompass
ene and retro-ene reactions. The implementationof ene chemistry required substantial …
ene and retro-ene reactions. The implementationof ene chemistry required substantial …
The aza-ene reaction of heterocyclic ketene aminals with enones: an efficient and simple synthetic route to fused di-and tri-heterocycles
JH Zhang, MX Wang, ZT Huang - Journal of the Chemical Society …, 1999 - pubs.rsc.org
Heterocyclic ketene aminals bearing a secondary amino moiety acted as hetero-ene
components to react with a number of enones under very mild conditions. The reaction of …
components to react with a number of enones under very mild conditions. The reaction of …
Carbonylative coupling of organozinc reagents in the presence and absence of aryl iodides: synthesis of unsymmetrical and symmetrical ketones
RFW Jackson, MH Block - Journal of the Chemical Society, Perkin …, 1997 - pubs.rsc.org
The utility of the palladium (0) catalysed reaction of the iodoalanine-derived organozinc
reagent 6a with functionalised aryl iodides, under a carbon monoxide atmosphere, to give …
reagent 6a with functionalised aryl iodides, under a carbon monoxide atmosphere, to give …
Oxidative and reductive carbodiazenylation of nonactivated olefins
MR Heinrich, O Blank, A Wetzel - The Journal of Organic …, 2007 - ACS Publications
Procedures for the carbodiazenylation of nonactivated olefins with a wide range of
aryldiazonium salts have been developed. The azo compounds obtained can serve as …
aryldiazonium salts have been developed. The azo compounds obtained can serve as …