Phospha-Mannich reactions of phosphinous acids R2P–OH and their derivatives
DV Moiseev - Phosphorus, Sulfur, and Silicon and the Related …, 2023 - Taylor & Francis
Secondary phosphine oxides R2P (O) H are a relatively stable tautomeric form of secondary
phosphinous acids R2P–OH that with imine/iminium species, or their donors, form …
phosphinous acids R2P–OH that with imine/iminium species, or their donors, form …
Three-Component Direct Phosphorylation of Aldehydes and Alkylation of Ketones: Synthesis of γ-Ketophosphine Oxides under Acidic Conditions
XH Wang, YW Xue, CY Bai, YB Wang… - The Journal of Organic …, 2023 - ACS Publications
An effective and economical acid-promoted three-component reaction for the construction of
C–P and C–C bonds for the synthesis of γ-ketophosphine oxides with water as the only …
C–P and C–C bonds for the synthesis of γ-ketophosphine oxides with water as the only …
An efficient direct phosphinylation and alkylation of ketones to construct C–P and C–C bonds: access to α, α-disubstituted γ-ketophosphine oxides
XH Wei, XH Wang, CY Bai, YW Xue, P Zhang… - Organic Chemistry …, 2023 - pubs.rsc.org
The first example of an acid-promoted difunctionalization of ketones to construct C–P and C–
C bonds via a phospha-aldol-elimination is described under metal-and solvent-free …
C bonds via a phospha-aldol-elimination is described under metal-and solvent-free …
Visible-Light-Induced α-C(sp3)–H Phosphinylation of Unactivated Ethers under Photocatalyst- and Additive-Free Conditions
B Liu, J Li, Y Hu, Q Chen, Y Liu, S Ji… - The Journal of …, 2022 - ACS Publications
A photocatalyst-and additive-free visible-light-induced α-C (sp3)–H phosphinylation of
unactivated ethers involving a C–O bond cleavage with molecular oxygen as the sole …
unactivated ethers involving a C–O bond cleavage with molecular oxygen as the sole …
Application of Primary Phosphine Oxides in Domino‐Phospha‐Aldol Reactions of Diketones
F Horký, C Bruhn, D Kargin… - Advanced Synthesis & …, 2024 - Wiley Online Library
An approach for the preparation and stabilization of primary phosphine oxides is presented
complementing previous methods of in situ generation. Specifically, RP (O) H2 where R …
complementing previous methods of in situ generation. Specifically, RP (O) H2 where R …
Catalyst‐ and Solvent‐Free Hydrophosphorylation of Aldimines with Secondary Phosphine Chalcogenides: Synthesis of Tertiary α‐Aminophosphine Oxides, Sulfides …
SN Arbuzova, SI Verkhoturova, SV Zinchenko… - …, 2022 - Wiley Online Library
Catalyst‐ and Solvent‐Free Hydrophosphorylation of Aldimines with Secondary Phosphine
Chalcogenides: Synthesis of Tertiary α‐Aminophosphine Oxides, Sulfides and Selenides …
Chalcogenides: Synthesis of Tertiary α‐Aminophosphine Oxides, Sulfides and Selenides …
Electrochemically oxidative phosphating of aldehydes and ketones
Y Ma, X Zhang, C Ma, W Xia, L Hu… - The Journal of Organic …, 2023 - ACS Publications
Disclosed herein is the first protocol for the electrochemically oxidative phosphating of
aldehydes and ketones to generate α-hydroxyphosphine oxides with diphenylphosphine as …
aldehydes and ketones to generate α-hydroxyphosphine oxides with diphenylphosphine as …
2-(Hydroxypropan-2-yl) diphenylphosphine oxide (HDPO): A convenient precursor to diphenylphosphine oxide (DPO)
JQ Zhang, M Gao, LB Han - Tetrahedron Letters, 2024 - Elsevier
A series of organophosphorus compounds including aryl, alkenyl and alkyl substituted
diphenylphosphine oxide derivatives Ph 2 P (O) R (R= aryl, alkenyl, alkyl), were prepared in …
diphenylphosphine oxide derivatives Ph 2 P (O) R (R= aryl, alkenyl, alkyl), were prepared in …
Synthesis of alkenylphosphine oxides via Tf 2 O promoted addition–elimination of ketones and secondary phosphine oxides
J Ma, L Wang, A Qiao, Z Li, F Zhao, J Wu - Organic & Biomolecular …, 2024 - pubs.rsc.org
Herein, we describe an efficient method for the synthesis of alkenylphosphine oxides via a
Tf2O promoted addition–elimination process. Various diarylphosphine oxides and …
Tf2O promoted addition–elimination process. Various diarylphosphine oxides and …
[PDF][PDF] Green-inspired synthetic drives for organophosphorus compounds under solvent-free conditions
G Brahmachari, I Karmakar - Arkivoc, 2022 - arkat-usa.org
Organophosphorus chemistry is an exciting field of research. Phosphorus-functionalized
organic molecules find practical and useful applications in such diverse areas as medicinal …
organic molecules find practical and useful applications in such diverse areas as medicinal …