Polyoxometalate (POM) based supramolecular assemblies have received significant
attention over recent years because of their unique and diverse redox and photochemical …

A great technological challenge facing our global future is the development of a secure,
clean, and renewable energy source. 1-4 Rising standards of living in a growing world …

Molecular metal oxide clusters, so-called polyoxometalates (POM) have been extensively
used as homogeneous photocatalysts in various photoredox reactions such as the oxidation …

An industrially applicable catalytic methodology for dihydrogen formation from a proton
source remains at the forefront of all efforts to replace the present fossil fuel economy by a …

Photocatalytic processes are applicable in wastewater treatment, energy production,
chemical synthesis, and greenhouse gas mitigation and thus have the potential to address …

The only sustainable energy source on earth is sunlight. Within one hour the current annual
energy demand of the world reaches the surface of earth as sunlight. Many concepts to …

Polyoxometalates (POMs) have peculiar optoelectronic properties and high reduction
potential, playing as excellent electron pools. Thus, during the recent decade, POMs have …

Haber-Bosch process to produce ammonia from hydrogenation of nitrogen is high energy
intensive and non-sustainable due to substantial CO 2 emissions primarily from the H 2 …

Recent developments in polyoxometalate photochemistry are discussed with a focus on
visible light driven productive chemical reactions. Special attention is given to the …

In spite of a high reduction potential of zero-valent Al (ZVAl), its ability to reduce Cr (VI), a
widespread pollutant, to less toxic Cr (III) remains to be uncovered. In the present study, Cr …