Optically active α-aminoalkylphosphonic acids 1 are structural analogues of α-amino acids
2, obtained by isosteric substitution of the planar and less bulky carboxylic acid (CO 2 H) by …

The synthesis of nitrogen-containing heterocycles, including natural alkaloids and other
compounds presenting different types of biological activities have proved to be successful …

A new mechanistic approach for the catalytic, enantioselective conjugate addition of
nitrogen-based nucleophiles to acceptor-substituted alkenes is reported, which is based on …

This report focuses on the utilization of N‐acylimines in addition reactions aimed at the
preparation of heterocyclic compounds. These can be directly obtained by reaction of N …

Phenylsulfone difluorodiazoethane (PhSO2CF2CHN2), an easy-to-prepare and bench-
stable masked CF2-building block, has been developed. The synthetic utility of this reagent …

A di-tert butyl peroxide (DTBP)-promoted α-alkylation of α-amino carbonyl compounds by
simple alkanes is developed, proceeding through dual sp3 C–H bonds cleavage. The …

N‐Activated ketimines are characterized by the presence of acyl, sulfonyl, and phosphinoyl
groups linked to the nitrogen atom of the azomethine system. These electron‐withdrawing …

An iron-catalyzed photochemical sulfinamidation of hydrocarbons with N-sulfinylamines has
been developed. The merger of ligand-to-metal charge transfer (LMCT) of FeCl3 with …

Triflic Acid Catalyzed 1,6‐Conjugate Addition of Thiols to p‐Quinone Methides under
Continuous‐Flow Conditions - Jadhav - 2017 - European Journal of Organic Chemistry …

The chemical transformation of phosphinic acid is a well-considered mature area of
research on account of the historical significant reactions such as Kabachnik–Fields …