Synthesis and functionalization of porphyrins through organometallic methodologies

S Hiroto, Y Miyake, H Shinokubo - Chemical reviews, 2017 - ACS Publications
This review focuses on the postfunctionalization of porphyrins and related compounds
through catalytic and stoichiometric organometallic methodologies. The employment of …

A voyage into the synthesis and photophysics of homo-and heterobinuclear ensembles of phthalocyanines and porphyrins

G de la Torre, G Bottari, M Sekita… - Chemical Society …, 2013 - pubs.rsc.org
The remarkable properties of both phthalocyanines and porphyrins as individual building
blocks have motivated the synthesis and study of homo-and heterobinuclear conjugates as …

[HTML][HTML] Macroheterocyclic compounds a key building block in new functional materials and molecular devices

OI Koifman, TA Ageeva, IP Beletskaya… - …, 2020 - cyberleninka.ru
The review discusses the latest advances in the directed synthesis and application of
macroheterocyclic compounds in science, engineering and technology, viz. as catalysts for …

Stirring the porphyrin alphabet soup—functionalization reactions for porphyrins

MO Senge - Chemical Communications, 2011 - pubs.rsc.org
Advances in the synthesis of unsymmetrically meso substituted porphyrins are based on the
development of new total syntheses and porphyrin functionalization methods. These …

Synthesis, spectral, and electrochemical studies of electronically tunable β-substituted porphyrins with mixed substituent pattern

R Kumar, M Sankar - Inorganic Chemistry, 2014 - ACS Publications
Two new families of porphyrins with mixed substituent pattern, viz. 2-nitro-12, 13-
disubstituted-meso-tetraphenylporphyrins (H2TPP (NO2) X2, X= Ph, phenylethynyl (PE), 2 …

Pd-catalyzed cross coupling strategy for functional porphyrin arrays

K Wang, A Osuka, J Song - ACS Central Science, 2020 - ACS Publications
Porphyrin arrays are an important class of compounds to study interporphyrin electronic
interactions that are crucial in determining the rates of energy transfer and electron transfer …

Synthesis of ferrocenyl porphyrins via suzuki coupling and their photophysical properties

MA Bakar, NN Sergeeva, T Juillard, MO Senge - Organometallics, 2011 - ACS Publications
In order to improve the synthetic access to ferrocene porphyrin type electron transfer
compounds, meso-ferrocenyl-appended porphyrins and bisporphyrins were prepared using …

Synthesis of 3, 20-disubstituted chlorophyll-a derivatives and reactivity of the substituents

H Tamiaki, N Ariki, H Sugiyama, Y Taira, Y Kinoshita… - Tetrahedron, 2013 - Elsevier
Abstract Methyl 20-bromo-pyropheophorbide-a possessing a vinyl group at the 3-position
and its analogs having 3-ethyl, 3-(1-hydroxyethyl) and 3-acetyl groups were prepared by …

β-substituted donor-acceptor porphyrins: Synthesis, energy transfer and electrochemical redox properties

N Grover, N Chaudhri, M Sankar - Dyes and Pigments, 2019 - Elsevier
Abstract β-substituted DA porphyrins have been synthesized via Suzuki coupling reaction
and characterized by various spectroscopic techniques. Two different electron donating …

5,10‐A2B2‐Type meso‐Substituted Porphyrins—A Unique Class of Porphyrins with a Realigned Dipole Moment

MO Senge, C Ryppa, M Fazekas… - … A European Journal, 2011 - Wiley Online Library
Current applications in porphyrin chemistry require the use of unsymmetrically substituted
porphyrins. Many current industrial interests in optics and biomedicine require systems with …