First-row d-block element-catalyzed carbon–boron bond formation and related processes
SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
modern synthetic organic chemistry, often affording unprecedented reactivity. The …
Methodologies and strategies for selective borylation of C–Het and C–C bonds
M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …
Synthesis of fluorinated compounds by Nickel-catalyzed defluorinative cross-coupling reactions
K Wang, W Kong - ACS Catalysis, 2023 - ACS Publications
Organofluorine compounds have attracted extensive attention in various industrial fields due
to their unique chemical and physical properties. Despite increasing demand in a wide …
to their unique chemical and physical properties. Despite increasing demand in a wide …
Diboron (4) compounds: from structural curiosity to synthetic workhorse
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …
(4) compounds been extensively explored. Many interesting structural features and reaction …
Site-selective cross-coupling of polyhalogenated arenes and heteroarenes with identical halogen groups
V Palani, MA Perea, R Sarpong - Chemical reviews, 2021 - ACS Publications
Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …
Base-free nickel-catalysed decarbonylative Suzuki–Miyaura coupling of acid fluorides
CA Malapit, JR Bour, CE Brigham, MS Sanford - Nature, 2018 - nature.com
Abstract The Suzuki–Miyaura cross-coupling of organoboron nucleophiles with aryl halide
electrophiles is one of the most widely used carbon–carbon bond-forming reactions in …
electrophiles is one of the most widely used carbon–carbon bond-forming reactions in …
Trends in the usage of bidentate phosphines as ligands in nickel catalysis
AL Clevenger, RM Stolley, J Aderibigbe… - Chemical …, 2020 - ACS Publications
A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …
Visible‐Light‐Induced Selective Defluoroborylation of Polyfluoroarenes, gem‐Difluoroalkenes, and Trifluoromethylalkenes
Fluorinated organoboranes serve as versatile synthetic precursors for the preparation of
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …
Copper-catalyzed regioselective monodefluoroborylation of polyfluoroalkenes en route to diverse fluoroalkenes
Monodefluoroborylation of polyfluoroalkenes has been achieved in a regioselective manner
under mild conditions via copper catalysis. The method has shown an extremely broad …
under mild conditions via copper catalysis. The method has shown an extremely broad …
Scalable, metal-and additive-free, photoinduced borylation of haloarenes and quaternary arylammonium salts
We report herein a simple, metal-and additive-free, photoinduced borylation of haloarenes,
including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids …
including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids …