First-row d-block element-catalyzed carbon–boron bond formation and related processes

SK Bose, L Mao, L Kuehn, U Radius… - Chemical …, 2021 - ACS Publications
Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Methodologies and strategies for selective borylation of C–Het and C–C bonds

M Wang, Z Shi - Chemical Reviews, 2020 - ACS Publications
Organoborons have emerged as versatile building blocks in organic synthesis to achieve
molecular diversity and as carboxylic acid bioisosteres with broad applicability in drug …

Synthesis of fluorinated compounds by Nickel-catalyzed defluorinative cross-coupling reactions

K Wang, W Kong - ACS Catalysis, 2023 - ACS Publications
Organofluorine compounds have attracted extensive attention in various industrial fields due
to their unique chemical and physical properties. Despite increasing demand in a wide …

Diboron (4) compounds: from structural curiosity to synthetic workhorse

EC Neeve, SJ Geier, IAI Mkhalid, SA Westcott… - Chemical …, 2016 - ACS Publications
Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Site-selective cross-coupling of polyhalogenated arenes and heteroarenes with identical halogen groups

V Palani, MA Perea, R Sarpong - Chemical reviews, 2021 - ACS Publications
Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …

Base-free nickel-catalysed decarbonylative Suzuki–Miyaura coupling of acid fluorides

CA Malapit, JR Bour, CE Brigham, MS Sanford - Nature, 2018 - nature.com
Abstract The Suzuki–Miyaura cross-coupling of organoboron nucleophiles with aryl halide
electrophiles is one of the most widely used carbon–carbon bond-forming reactions in …

Trends in the usage of bidentate phosphines as ligands in nickel catalysis

AL Clevenger, RM Stolley, J Aderibigbe… - Chemical …, 2020 - ACS Publications
A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …

Visible‐Light‐Induced Selective Defluoroborylation of Polyfluoroarenes, gem‐Difluoroalkenes, and Trifluoromethylalkenes

W Xu, H Jiang, J Leng, HW Ong, J Wu - Angewandte Chemie, 2020 - Wiley Online Library
Fluorinated organoboranes serve as versatile synthetic precursors for the preparation of
value‐added fluorinated organic compounds. Recent progress has been mainly focused on …

Copper-catalyzed regioselective monodefluoroborylation of polyfluoroalkenes en route to diverse fluoroalkenes

H Sakaguchi, Y Uetake, M Ohashi, T Niwa… - Journal of the …, 2017 - ACS Publications
Monodefluoroborylation of polyfluoroalkenes has been achieved in a regioselective manner
under mild conditions via copper catalysis. The method has shown an extremely broad …

Scalable, metal-and additive-free, photoinduced borylation of haloarenes and quaternary arylammonium salts

AM Mfuh, JD Doyle, B Chhetri, HD Arman… - Journal of the …, 2016 - ACS Publications
We report herein a simple, metal-and additive-free, photoinduced borylation of haloarenes,
including electron-rich fluoroarenes, as well as arylammonium salts directly to boronic acids …