Three decades of unveiling the complex chemistry of C-nitroso species with computational chemistry
P Bianchi, JCM Monbaliu - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
C-Nitroso species are characterized by a unique nitrogen–oxygen combination located next
to a carbon backbone, which confers them a unique ambiphilic and high reactivity towards …
to a carbon backbone, which confers them a unique ambiphilic and high reactivity towards …
On Demand Flow Platform for the Generation of Anhydrous Dinitrogen Trioxide and Its Further Use in N‐Nitrosative Reactions
Y Chen, S Renson, JCM Monbaliu - Angewandte Chemie, 2022 - Wiley Online Library
Abstract Dinitrogen trioxide (N2O3) is a powerful and efficient nitrosating agent that comes
with an unprecedented atom economy. However, the synthetic application of N2O3 is still …
with an unprecedented atom economy. However, the synthetic application of N2O3 is still …
A modular, low footprint and scalable flow platform for the expedient α-aminohydroxylation of enolizable ketones
The unique reactivity profile of α-chloronitroso derivatives is expressed to its fullest potential
through the development of an integrated, modular and scalable continuous flow process for …
through the development of an integrated, modular and scalable continuous flow process for …
Preparation, Reactivity, and Synthetic Utility of Simple Benzotriazole Derivatives
R Gérardy, JCM Monbaliu - The Chemistry of Benzotriazole Derivatives: A …, 2016 - Springer
The benzotriazole fragment is known to behave as (1) an excellent leaving group,(2) an
electron-donating or an electron-withdrawing group,(3) an anion precursor, and (4) a radical …
electron-donating or an electron-withdrawing group,(3) an anion precursor, and (4) a radical …
One pot conversion of benzophenone imine into the relevant 2-aza-allenium
M Bortoluzzi, T Funaioli, F Marchetti… - Chemical …, 2017 - pubs.rsc.org
Interaction of common imines with WCl6 in organic solvents revealed very unusual features
in the context of imine chemistry. Ph2CNH was converted in one pot into the 2-aza-allenium …
in the context of imine chemistry. Ph2CNH was converted in one pot into the 2-aza-allenium …