Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

Methods to functionalize arenes and heteroarenes in a site-selective manner are highly
sought after for rapidly constructing value-added molecules of medicinal, agrochemical, and …

Fluorine has received great attention in all fields of science.“Small atom with a big ego” was
the title of the Symposium at the ACS meeting in San Francisco in 2000, where a number of …

Two protocols for the nickel-catalyzed cross-coupling of aryl fluorides with aryl boronic
esters have been developed. The first employs metal fluoride cocatalysts, such as ZrF4 and …

C–F bond activation is currently considered to be “a hot topic” in many different but
interconnected fields of research, due to its inherent inertness and unique properties. While …

We report a dual-tasked methylation that is based on cooperative palladium/norbornene
catalysis. Readily available (hetero) aryl halides (39 iodides and 4 bromides) and …

Cross coupling reactions of polyfluoroarenes via C–F activation - Dalton Transactions (RSC
Publishing) DOI:10.1039/C0DT00540A Royal Society of Chemistry View PDF VersionPrevious …

The reaction of [Ni2 (i Pr2Im) 4 (COD)] 1a or [Ni (i Pr2Im) 2 (η2-C2H4)] 1b with different
fluorinated arenes is reported. These reactions occur with a high chemo-and regioselectivity …

Abstract The nickel‐mediated [3+ 2] cycloaddition of 2‐trifluoromethyl‐1‐alkenes with
alkynes afforded fluorine‐containing multi‐substituted cyclopentadienes in a regioselective …

Fluorinated compounds have become an important class of compounds due to extensive
use of fluoro-compounds in diverse fields such as pharmaceuticals, agrochemicals, catalysis …