Various features of melt strain hardening of polymeric materials in uniaxial extension and their relation to molecular structure: review of experimental results and their …

H Münstedt - Rheologica Acta, 2023 - Springer
Strain hardening of polymer melts is able to improve the uniformity of items in processing
operations with elongational deformation. Of particular interest in this aspect is the …

Polymer extension flows and instabilities

AY Malkin, A Arinstein, VG Kulichikhin - Progress in Polymer Science, 2014 - Elsevier
The basics of the uniaxial stretching of polymer melts and solutions are considered,
including analysis of the transient regimes of deformation, as well as the different types of …

When polymer chains are highly aligned: a perspective on extensional rheology

Q Huang - Macromolecules, 2022 - ACS Publications
We provide a Perspective on recent findings in extensional rheology for polymer melts and
solutions with different macromolecular architectures. For linear polymer systems, we focus …

Elongational viscosity of monodisperse and bidisperse polystyrene melts

JK Nielsen, HK Rasmussen, O Hassager… - Journal of …, 2006 - pubs.aip.org
The start-up and steady uniaxial elongational viscosity have been measured for two
monodisperse polystyrene melts with molecular weights of 52 and 103 kg∕ mole, and for …

[HTML][HTML] Complex polymer topologies in blends: shear and elongational rheology of linear/pom-pom polystyrene blends

V Hirschberg, S Lyu, MG Schußmann - Journal of Rheology, 2023 - pubs.aip.org
The shear and elongational rheology of linear and pom-pom shaped polystyrene (PS)
blends was investigated experimentally and modeled using constitutive models such as the …

Modeling elongational viscosity of polystyrene Pom-Pom/linear and Pom-Pom/star blends

V Hirschberg, S Lyu, MG Schußmann, M Wilhelm… - Rheologica Acta, 2023 - Springer
The elongational rheology of blends of a polystyrene (PS) Pom-Pom with two linear
polystyrenes was recently reported by Hirschberg et al.(J. Rheol. 2023, 67: 403–415). The …

Rheology of Poly (α-olefin) Bottlebrushes: Effect of Self-Dilution by Alkane Side Chains

MH Wagner, V Hirschberg - Macromolecules, 2024 - ACS Publications
Bottlebrush polymers are combs with extremely high grafting density along their backbone
chain. We consider the rheology of bottlebrush poly (α-olefins) with side chains ranging from …

Studying the origin of “strain hardening”: Basic difference between extension and shear

G Liu, H Sun, S Rangou, K Ntetsikas… - Journal of …, 2013 - pubs.aip.org
This work studies the origin of the so called" strain hardening" observed when comparing
the transient stress response of entangled melts to uniaxial extension with that to simple …

Comparison of the elongational behavior of various polyolefins in uniaxial and equibiaxial flows

FJ Stadler, A Nishioka, J Stange, K Koyama… - Rheologica acta, 2007 - Springer
For processing operations with a pronounced elongational component, it was found that the
uniformity of extruded items is improved by the presence of strain hardening usually …

Rheological and molecular characterization of long-chain branched poly (ethylene terephthalate)

M Kruse, MH Wagner - Rheologica Acta, 2017 - Springer
Reactive extrusion with pyromellitic dianhydride (PMDA) and tetraglycidyl diamino diphenyl
methane (TGDDM) was conducted to create long-chain branched poly (ethylene …