Herein, we report a synthesis of cyclohexanones bearing multi‐continuous stereocenters by
combining copper‐catalyzed asymmetric conjugate addition of dialkylzinc reagents to cyclic …

Asymmetric cross‐couplings based on 1, 2‐carbon migration from B‐ate complexes have
been developed efficiently to access valuable organoboronates. However, enantioselective …

Asymmetric reactions that convert racemic mixtures into enantioenriched amines are of
significant importance due to the prevalence of amines in pharmaceuticals, with about 60 …

The diastereo‐and enantioselective construction of vicinal all‐carbon quaternary
stereocenters is a formidable task. We here report a synergistic bimetallic catalysis via a …

Both polycyclic pyrimidin-4-one synthesis and the dehydrogenative coupling of malonates
often require a redox agent, an elevated temperature, large amounts of transition-metal …

Ring‐opening transformations of donor‐acceptor (D‐A) cyclopropanes enable the rapid
assembly of complex molecules. However, the enantioselective formation of chiral …

A palladium-catalyzed enantioselective decarboxylative allylic alkylation of α-benzyl
cyanoacetates with methylene cyclic carbamates has been successfully developed. An array …

Herein, we present the formation of acyclic frameworks bearing two consecutive
stereocenters of either tertiary or quaternary nature starting from easily accessible …

The development of catalytic and enantioselective transformations for the synthesis of all-
carbon quaternary stereocenters has long been recognized as a significant challenge in …

The involvement of planar carbocation intermediates is generally considered undesirable in
asymmetric catalysis due to the difficulty in gaining facial control and their intrinsic stability …