Metal–metal bond in lanthanide single-molecule magnets

Z Zhu, J Tang - Chemical Society Reviews, 2022 - pubs.rsc.org
Lanthanide (Ln) compounds represent a unique chemical platform for developing high-
temperature single-molecule magnets (SMMs). The shift in research focus from increasing …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Synthesis and magnetism of neutral, linear metallocene complexes of terbium (II) and dysprosium (II)

CA Gould, KR McClain, JM Yu… - Journal of the …, 2019 - ACS Publications
The divalent metallocene complexes Ln (CpiPr5) 2 (Ln= Tb, Dy) were synthesized through
the KC8 reduction of Ln (CpiPr5) 2I intermediates and represent the first examples of …

Insight into D6h Symmetry: Targeting Strong Axiality in Stable Dysprosium(III) Hexagonal Bipyramidal Single‐Ion Magnets

AB Canaj, S Dey, ER Martí, C Wilson… - Angewandte Chemie …, 2019 - Wiley Online Library
Following a novel synthetic strategy where the strong uniaxial ligand field generated by the
Ph3SiO−(Ph3SiO−= anion of triphenylsilanol) and the 2, 4‐di‐tBu‐PhO−(2, 4‐di‐tBu‐PhO …

Lanthanide single-molecule magnets with high anisotropy barrier: where to from here?

Z Zhu, J Tang - National Science Review, 2022 - academic.oup.com
Lanthanide single-molecule magnets with high anisotropy barrier: where to from here? |
National Science Review | Oxford Academic Skip to Main Content Advertisement Oxford …

Two Metastable Endohedral Metallofullerenes Sc2C2@C1(39656)-C82 and Sc2C2@C1(51383)-C84: Direct-C2-Insertion Products from Their Most …

YR Yao, ZC Chen, L Chen, SY Zheng… - Journal of the …, 2023 - ACS Publications
Endohedral metallofullerenes (EMFs) are sub-nano carbon materials with diverse
applications, yet their formation mechanism, particularly for metastable isomers, remains …

High-temperature magnetic blocking in a monometallic dysprosium azafullerene single-molecule magnet

Z Hu, Y Wang, A Ullah, GM Gutiérrez-Finol… - Chem, 2023 - cell.com
Single-molecule magnets (SMMs) showing magnetic blocking near or above liquid nitrogen
temperature have recently been achieved by inducing exceptionally strong and axial crystal …

Development of Single‐Molecule Magnets

D Shao, XY Wang - Chinese Journal of Chemistry, 2020 - Wiley Online Library
Single‐molecule magnets (SMMs) are paramagnetic molecules that can be magnetized
below a certain temperature and have potential applications in high‐density information …

Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets

A Swain, T Sharma, G Rajaraman - Chemical Communications, 2023 - pubs.rsc.org
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …

Steering Single-Electron Metal–Metal Bonds and Hyperfine Coupling between a Transition Metal-Lanthanide Heteronuclear Bimetal Confined in Carbon Cages

W Xiang, Z Hu, J Xin, H Jin, Z Jiang, X Han… - Journal of the …, 2023 - ACS Publications
Metal complexes bearing single-electron metal–metal bonds (SEMBs) exhibit unusual
electronic structures evoking strong magnetic coupling, and such bonds can be stabilized in …