There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …

This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …

Zero-dimensional cluster complexes and coordination polymers for magnetic refrigeration
have attracted great interest in the last decade. In-situ synthesis is a widely-used method to …

Recent years have witnessed a terrific increase in the number of molecule-based materials
proposed as magnetic refrigerants for liquid-helium temperatures.[1–15] Refrigeration …

Molecular nanomagnets are considered valid candidates for magnetic refrigeration at low
temperatures. Designing these materials for enhanced cooling requires the control and …

The synthesis, structures, and magnetic properties of six families of cobalt–lanthanide mixed-
metal phosphonate complexes are reported in this Article. These six families can be divided …

Molecoolers: An unprecedentedly large cryogenic magnetocaloric effect is observed in
gadolinium acetate tetrahydrate (see picture, Gd pink, O red, C gray). The change in its …

New dinuclear lanthanide (III) complexes based on an 8-hydroxyquinoline Schiff base
derivative and β-diketonate ligands,[Ln2 (hfac) 4 (L) 2](Ln (III)= Gd (1), Tb (2), Dy (3), Ho (4) …

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Magnetic refrigeration is based on the magnetocaloric effect (MCE) which relies on the
entropy change of a material when placed in a magnetic field. 1 Molecular magnets have …