Bioinspired applications of porphyrin derivatives

JM Park, KI Hong, H Lee, WD Jang - Accounts of chemical …, 2021 - ACS Publications
Conspectus Porphyrin derivatives are ubiquitous in nature and have important biological
roles, such as in light harvesting, oxygen transport, and catalysis. Owing to their intrinsic π …

[HTML][HTML] Artificial molecular machines

S Erbas-Cakmak, DA Leigh, CT McTernan… - Chemical …, 2015 - ACS Publications
The widespread use of molecular machines in biology has long suggested that great
rewards could come from bridging the gap between synthetic molecular systems and the …

Stimuli-responsive metal–ligand assemblies

AJ McConnell, CS Wood, PP Neelakandan… - Chemical …, 2015 - ACS Publications
Within living systems, molecular-scale responses to stimuli flow together into the intricate
and robust signal transduction networks that process information for an organism. Studies of …

Nonbiaryl and heterobiaryl atropisomers: molecular templates with promise for atropselective chemical transformations

E Kumarasamy, R Raghunathan, MP Sibi… - Chemical …, 2015 - ACS Publications
Chirality plays a crucial role in life-sustaining processes, and for this reason asymmetric
synthesis has been a central research theme in many research groups in the field of organic …

Optically active porphyrin and phthalocyanine systems

H Lu, N Kobayashi - Chemical reviews, 2016 - ACS Publications
This review highlights and summarizes various optically active porphyrin and
phthalocyanine molecules prepared using a wide range of structural modification methods …

Assessing cooperativity in supramolecular systems

LKS von Krbek, CA Schalley… - Chemical Society Reviews, 2017 - pubs.rsc.org
This tutorial review summarises different aspects of cooperativity in supramolecular
complexes. We propose a systematic categorisation of cooperativity into cooperative …

Binding mechanisms in supramolecular complexes

HJ Schneider - Angewandte Chemie International Edition, 2009 - Wiley Online Library
Forces to reckon with: Supramolecular complexes, such as the one shown, are normally
based on a combination of different interactions such as ion pairing, hydrogen bonds, and …

Enzyme mimics based upon supramolecular coordination chemistry

MJ Wiester, PA Ulmann… - Angewandte Chemie …, 2011 - Wiley Online Library
Recent advances in supramolecular coordination chemistry have allowed chemists to
synthesize macromolecular complexes that exhibit various properties intrinsic to enzymes …

Synthetic molecular motors and mechanical machines

ER Kay, DA Leigh, F Zerbetto - … Chemie International Edition, 2007 - Wiley Online Library
The widespread use of controlled molecular‐level motion in key natural processes suggests
that great rewards could come from bridging the gap between the present generation of …

What is cooperativity?

C Hunter, H Anderson - Angewandte Chemie (International ed. in …, 2009 - ora.ox.ac.uk
The lamprey holds the clue to the link between supramolecular self-assembly and allosteric
ligand binding. Chelate cooperativity in self-assembled structures results in denaturation …