Water at interfaces

O Björneholm, MH Hansen, A Hodgson… - Chemical …, 2016 - ACS Publications
The interfaces of neat water and aqueous solutions play a prominent role in many
technological processes and in the environment. Examples of aqueous interfaces are …

Probing liquid/solid interfaces at the molecular level

F Zaera - Chemical reviews, 2012 - ACS Publications
The ability to obtain a molecular-level understanding of the chemistry that takes place at
liquid/solid interfaces is key to the development and improvement of many chemical and …

Mineral–water interface reactions of actinides

H Geckeis, J Lützenkirchen, R Polly, T Rabung… - Chemical …, 2013 - ACS Publications
Reactions of the light actinide ions (Th to Cm) at the mineral− aqueous solution interface
have attracted much attention during recent years. Initially research was mainly driven by the …

Correlation between electrostatic and hydration forces on silica and gibbsite surfaces: An atomic force microscopy study

A Klaassen, F Liu, F Mugele, I Siretanu - Langmuir, 2022 - ACS Publications
The balance between hydration and Derjaguin–Landau–Verwey–Overbeek (DLVO) forces
at solid–liquid interfaces controls many processes, such as colloidal stability, wetting …

Toward informed design of nanomaterials: a mechanistic analysis of structure–property–function relationships for faceted nanoscale metal oxides

HE Rudel, MKM Lane, CL Muhich, JB Zimmerman - ACS nano, 2020 - ACS Publications
Nanoscale metal oxides (NMOs) have found wide-scale applicability in a variety of
environmental fields, particularly catalysis, gas sensing, and sorption. Facet engineering, or …

Formation, stability, and solubility of metal oxide nanoparticles: Surface entropy, enthalpy, and free energy of ferrihydrite

T Hiemstra - Geochimica et Cosmochimica Acta, 2015 - Elsevier
Ferrihydrite (Fh) is an excellent model for understanding nanoparticle behavior in general.
Moreover, Fh is one of the most important Fe (hydr) oxides in nature. Fh particles can be …

Monovalent ion adsorption at the muscovite (001)–solution interface: Relationships among ion coverage and speciation, interfacial water structure, and substrate …

SS Lee, P Fenter, KL Nagy, NC Sturchio - Langmuir, 2012 - ACS Publications
The interfacial structure between the muscovite (001) surface and aqueous solutions
containing monovalent cations (3× 10–3 m Li+, Na+, H3O+, K+, Rb+, or Cs+, or 3× 10–2 m …

Interaction of anionic pollutants with Al-based adsorbents in aqueous media–A review

E Kumar, A Bhatnagar, W Hogland, M Marques… - Chemical Engineering …, 2014 - Elsevier
Many anionic pollutants (eg, fluoride, nitrate and nitrite, bromate, phosphate, arsenate and
arsenite, selenate and selenite, perchlorate) have been detected in surface and …

Three-dimensional ordering of water molecules reflecting hydroxyl groups on sapphire (001) and α-quartz (100) surfaces

S Nagai, S Urata, K Suga, T Fukuma, Y Hayashi… - Nanoscale, 2023 - pubs.rsc.org
Water molecules on oxide surfaces influence the chemical reactivity and molecular
adsorption behavior of oxides. Herein, three-dimensional atomic force microscopy (3D-AFM) …

Mechanisms of chromate adsorption on hematite

CP Johnston, M Chrysochoou - Geochimica et Cosmochimica Acta, 2014 - Elsevier
The fate of chromate in subsurface environments is strongly affected by adsorption reactions
on iron oxide surfaces. Characterization of adsorption mechanisms is needed to formulate …