Eliciting High‐Performance Thermoelectric Materials via Phase Diagram Engineering: A Review
Thermoelectric (TE) materials and devices have been a promising green technology since
the 1960s. Enormous research efforts bring forth TE generator and TE refrigerator, in which …
the 1960s. Enormous research efforts bring forth TE generator and TE refrigerator, in which …
Phase transformation contributions to heat capacity and impact on thermal diffusivity, thermal conductivity, and thermoelectric performance
The accurate characterization of thermal conductivity κ, particularly at high temperature, is of
paramount importance to many materials, thermoelectrics in particular. The ease and access …
paramount importance to many materials, thermoelectrics in particular. The ease and access …
New Trick for an Old Dog: From Prediction to Properties of “Hidden Clathrates” Ba2Zn5As6 and Ba2Zn5Sb6
The zinc–antimony phase space has been heavily investigated due to the structural
complexity and abundance of high-performing thermoelectric materials. Consequentially …
complexity and abundance of high-performing thermoelectric materials. Consequentially …
Kirkendall effect induced ultralow thermal conductivity yields enhanced thermoelectric properties in Mg–Zn–Sb alloys
Thermally induced phase change can modify the microstructure of thermoelectric alloys due
to the interdiffusion of atomic species, and also to alter the properties of these materials …
to the interdiffusion of atomic species, and also to alter the properties of these materials …
Fast ion transport for synthesis and stabilization of β-Zn4Sb3
Mobile ion-enabled phenomena make β-Zn4Sb3 a promising material in terms of the re-
entry phase instability behavior, mixed electronic ionic conduction, and thermoelectric …
entry phase instability behavior, mixed electronic ionic conduction, and thermoelectric …
Operando X-ray scattering study of segmented thermoelectric Zn 4 Sb 3
PS Thorup, RS Christensen, M Roelsgaard… - Journal of Materials …, 2023 - pubs.rsc.org
The inexpensive and high-performing thermoelectric material β-Zn4Sb3 is a mixed ionic-
electronic conductor, which suffers from stability issues due to Zn migration in the structure …
electronic conductor, which suffers from stability issues due to Zn migration in the structure …
Weak Bonding and Anharmonicity in Thermoelectric ZnSb
TBE Grønbech, H Kasai, J Zhang… - Advanced Functional …, 2024 - Wiley Online Library
Abstract The Zn─ Sb binary system contains two high‐performing thermoelectric materials,
namely the ordered ZnSb and the disordered Zn13Sb10. Both systems exhibit low thermal …
namely the ordered ZnSb and the disordered Zn13Sb10. Both systems exhibit low thermal …
From NaZn4Sb3 to HT-Na1–xZn4–ySb3: Panoramic Hydride Synthesis, Structural Diversity, and Thermoelectric Properties
V Gvozdetskyi, B Owens-Baird, S Hong… - Chemistry of …, 2019 - ACS Publications
Two new sodium zinc antimonides NaZn4Sb3 and HT-Na1–x Zn4–y Sb3 were synthesized
by using reactive sodium hydride, NaH, as a precursor. The hydride route provides uniform …
by using reactive sodium hydride, NaH, as a precursor. The hydride route provides uniform …
Improving the Operational Stability of Thermoelectric Zn4Sb3 by Segmentation
PS Thorup, CM Zeuthen, KA Borup… - Chemistry of …, 2022 - ACS Publications
The mixed ionic–electronic conductor β-Zn4Sb3 is a cheap and high-performing
thermoelectric material, but under operating conditions with a temperature gradient and a …
thermoelectric material, but under operating conditions with a temperature gradient and a …
Stability and Thermoelectric Properties of Zn4Sb3 with TiO2 Nanoparticle Inclusions
KFF Fischer, JH Bjerg, LR Jørgensen… - ACS applied materials …, 2021 - ACS Publications
β-Zn4Sb3 is a cheap nontoxic high-performance thermoelectric material, which
unfortunately suffers from stability issues because of zinc migration in thermal and electrical …
unfortunately suffers from stability issues because of zinc migration in thermal and electrical …