Synthesis of Ir (iii) complexes with Tp Me2 and acac ligands and their reactivity with electrophiles

JP Morales-Cerón, V Salazar-Pereda… - Dalton …, 2015 - pubs.rsc.org
The reaction of the bis (ethylene) complex [TpMe2Ir (C2H4) 2](1)(TpMe2= hydrotris (3, 5-
dimethylpyrazolyl) borate) with an excess of 2, 4-pentanedione (acetylacetone, Hacac) at …

Activation of aldehydes by exocyclic iridium (i)-η 4: π 2-diene complexes derived from 1, 3-oxazolidin-2-ones

R Padilla, V Salazar-Pereda… - Dalton …, 2016 - pubs.rsc.org
The Ir (I) complexes [TpMe2Ir (η4-1, 4-diene)] 2b and 2c react thermally with a variety of
aromatic aldehydes, 3a–e, to generate the metallabicyclic compounds 4e–k and the Fischer …

Reaction cascade: Ortho-C–H activation and C–C coupling of benzophenone leading to tetranuclear organoiron and mononuclear organocobalt complexes

R Beck, S Camadanli, U Floerke, HF Klein - Journal of Organometallic …, 2015 - Elsevier
The novel tetranuclear mixed valent iron (II)/iron (0) complex (1) was prepared by ortho-
metalation of benzophenone with zerovalent Fe (PMe 3) 4 (d 8) followed by a subsequent …

Synthesis and Diels–Alder Cycloadditions of exo-Imidazolidin-2-one Dienes

R Bautista, P Bernal, R Herrera… - The Journal of …, 2011 - ACS Publications
An efficient and versatile synthesis of novel exo-imidazolidin-2-one dienes is described. This
involves the base-assisted condensation/cyclization cascade reaction of the monoimino …

Reactivity of N‐Substituted Exo‐oxazolidin‐2‐one Dienes with Naphthalene Chalcones and Cyclic 1,3‐Dicarbonyl Compounds

S Mastachi‐Loza… - Asian Journal of …, 2018 - Wiley Online Library
Abstract The N‐substituted exo‐2‐oxazolidinone dienes are versatile molecules that
undergo a variety of reactions. To further explore this versatility, Diels‐Alder reactions were …

Reactivity of 2‐mercaptopyridines with Iridium (I)‐Tris (pyrazolyl) borate complexes

MA Gomez‐Bonilla, V Salazar‐Pereda… - European Journal of …, 2021 - Wiley Online Library
Reaction of of the Ir (I) complex [TpMe2Ir−(C2H4) 2](1) with a variety of mercaptopyridines
produces in good yields the Ir (III)‐metallacycles 2–4 with the general formula [TpMe2Ir …

Synthesis and Reactivity of η4-Diene-Fe(CO)3 Complexes from exo-2-Oxazolidinone Dienes. A Facile Generation of Stable Conjugated Enol-Enamido Species

F Ortega-Jiménez, A Benavides, F Delgado… - …, 2010 - ACS Publications
A synthesis of new η4-diene-Fe (CO) 3 complexes derived from the novel exo-2-
oxazolidinone dienes is described. These complexes were prepared by thermal …

Reactividad de dienos exo-oxazolidin-2-ona N-sustituidos con naftoquinonas y chalconas.

S Mastachi Loza - 2018 - ri.uaemex.mx
La reacción de Diels-Alder es una metodología que se ha utilizado desde su
descubrimiento hasta la actualidad como uno de los métodos más importantes para la …

Activación de dienos, aldehídos y alquinos para la formación de iridaciclos, mediante complejos organometálicos de iridio y TpMe2.

RM Padilla Paz - 2010 - dgsa.uaeh.edu.mx
8.“Síntesis y estudio de complejos organometálicos de iridio con 1, 3-oxazolidin-2-onas N-
sustituidas” presentado en el marco de las actividades científicas del XLIV Congreso …