The Pd‐catalyzed coupling of aryl (pseudo) halides and amines is one of the most powerful
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …

Conspectus Cyclometalated π-allyliridium-C, O-benzoate complexes discovered in the
Krische laboratory display unique amphiphilic properties, catalyzing both nucleophilic …

Dialkylbiaryl phosphines are a valuable class of ligand for Pd-catalyzed amination reactions
and have been applied in a range of contexts. This perspective attempts to aid the reader in …

Earth-abundant metal (EAM) catalysis can have profound impact in the pharmaceutical
industry in terms of sustainability and cost improvements from replacing precious metals like …

Carbon–Heteroatom Coupling Using Pd-PEPPSI Complexes | Organic Process Research &
Development ACS ACS Publications C&EN CAS Find my institution Log In Organic Process …

The Buchwald–Hartwig C–N coupling reaction has been ranked as one of the 20 most
frequently used reactions in medicinal chemistry. Owing to its much lower cost and higher …

Due to the low intrinsic acidity of amines, palladium-catalyzed C–N cross-coupling has been
plagued continuously by the necessity to employ strong, inorganic, or insoluble bases. To …

We describe a systematic study of the scope and relationship between ligand structure and
activity for a highly efficient and selective class of catalysts containing sterically hindered …

A new air-stable nickel precatalyst for C–N cross-coupling is reported. The developed
catalyst system displays a greatly improved substrate scope for C–N bond formation to …

We report that the complex generated from Pd [P (o-tol) 3] 2 and the alkylbisphosphine CyPF-
t-Bu is a highly active and selective catalyst for the coupling of ammonia with aryl chlorides …