Large anion binding in water

KI Assaf, WM Nau - Organic & Biomolecular Chemistry, 2023 - pubs.rsc.org
Large water-soluble anions with chaotropic character display surprisingly strong
supramolecular interactions in water, for example, with macrocyclic receptors, polymers …

Chemistry of Carbon-Substituted Derivatives of Cobalt Bis(dicarbollide)(1) Ion and Recent Progress in Boron Substitution

L Pazderová, EZ Tüzün, D Bavol, M Litecká, L Fojt… - Molecules, 2023 - mdpi.com
The cobalt bis (dicarbollide)(1−) anion (1−),[(1, 2-C2B9H11) 2-3, 3′-Co (III)](1−), plays an
increasingly important role in material science and medicine due to its high chemical …

All‐Inorganic Polyoxometalates Act as Superchaotropic Membrane Carriers

A Barba‐Bon, NI Gumerova, E Tanuhadi… - Advanced …, 2024 - Wiley Online Library
Polyoxometalates (POMs) are known antitumoral, antibacterial, antiviral, and anticancer
agents and considered as next‐generation metallodrugs. Herein, a new biological …

A small-molecule carrier for the intracellular delivery of a membrane-impermeable protein with retained bioactivity

X Ma, Z Zhang, A Barba-Bon, D Han, Z Qi, B Ge… - Proceedings of the …, 2024 - pnas.org
Intracellular protein delivery has the potential to revolutionize cell-biological research and
medicinal therapy, with broad applications in bioimaging, disease treatment, and genome …

Size and polarizability of boron cluster carriers modulate chaotropic membrane transport

G Salluce, Y Folgar‐Cameán, A Barba‐Bon… - Angewandte …, 2024 - Wiley Online Library
Perhalogenated closo‐borates represent a new class of membrane carriers. They owe this
activity to their chaotropicity, which enables the transport of hydrophilic molecules across …

Boron Cluster Anions Dissolve En Masse in Lipids Causing Membrane Expansion and Thinning

A Barba‐Bon, A El Haitami, C Pasquier… - Angewandte …, 2024 - Wiley Online Library
Boron clusters are applied in medicinal chemistry because of their high stability in biological
environments and intrinsic ability to capture neutrons. However, their intermolecular …

Cobaltabis (dicarbollide) Interaction with DNA Resolved at the Atomic Scale

D Halder, AMA Abdelgawwad… - Journal of Medicinal …, 2024 - ACS Publications
Boron neutron capture therapy represents a promising avenue for cancer treatment that
requires nontoxic drugs with a high boron content efficiently distributed into cancerous cells …

Boron Clusters Alter the Membrane Permeability of Dicationic Fluorescent DNA-Staining Dyes

Y Hirai, Y Makita, J Asaoka, Y Aoyagi, A Nomoto… - Acs Omega, 2023 - ACS Publications
Membrane-permeable fluorescent dyes that stain DNA are useful reagents for microscopic
imaging, as they can be introduced into living cells to label DNA. However, the number of …

Metallacarboranes in Medicinal Chemistry: Current Advances and Future Perspectives

M Gos, J Cebula, TM Goszczyński - Journal of Medicinal …, 2024 - ACS Publications
Metallacarboranes, exemplified by cobalt bis (dicarbollide)([COSAN]−), have excelled their
historical metallocene analogue label to become promising in drug design, medical studies …

[HTML][HTML] Enhancing Membrane Permeability of Fluorescein-Type Chromophore Through Covalent Attachment of Chlorinated Dodecaborate

H Nakamura, S Yamamoto, YK Kawamura, T Kitazawa… - Molecules, 2024 - mdpi.com
Anionic boron clusters, such as [B12X12] 2−(X= Cl, Br, I), have attracted attention in
pharmaceuticals due to their unique superchaotropic properties. In particular,[B12Br12] …