Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis

KY Wang, J Zhang, YC Hsu, H Lin, Z Han… - Chemical …, 2023 - ACS Publications
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

J Liu, TA Goetjen, Q Wang, JG Knapp… - Chemical Society …, 2022 - pubs.rsc.org
A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-
scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and …

MOF-based membranes for gas separations

Q Qian, PA Asinger, MJ Lee, G Han… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs) represent the largest known class of porous crystalline
materials ever synthesized. Their narrow pore windows and nearly unlimited structural and …

Understanding the Effect of Water on CO2 Adsorption

JM Kolle, M Fayaz, A Sayari - Chemical Reviews, 2021 - ACS Publications
Carbon capture from large sources and ambient air is one of the most promising strategies
to curb the deleterious effect of greenhouse gases. Among different technologies, CO2 …

Metal–organic framework-based catalysts with single metal sites

YS Wei, M Zhang, R Zou, Q Xu - Chemical Reviews, 2020 - ACS Publications
Metal–organic frameworks (MOFs) are a class of distinctive porous crystalline materials
constructed by metal ions/clusters and organic linkers. Owing to their structural diversity …

Microporous metal-organic framework materials for gas separation

RB Lin, S Xiang, W Zhou, B Chen - Chem, 2020 - cell.com
Gas separation is a very important industrial process for manufacturing chemicals, fuels,
plastics, and polymers but is also energy intensive through the traditional cryogenic …

Advances in metal–organic framework-based nanozymes and their applications

X Huang, S Zhang, Y Tang, X Zhang, Y Bai… - Coordination Chemistry …, 2021 - Elsevier
Nanozymes bridge the fields of inorganic nanomaterials and biology and have attracted
wide attention. Nanozymes have the catalytic capabilities of inorganic materials at the …

Porous metal-organic frameworks for gas storage and separation: Status and challenges

H Li, L Li, RB Lin, W Zhou, Z Zhang, S Xiang, B Chen - EnergyChem, 2019 - Elsevier
Gases are widely used as energy resources for industry and our daily life. Developing
energy cost efficient porous materials for gas storage and separation is of fundamentally and …

Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis

W Xu, Y Wu, W Gu, D Du, Y Lin, C Zhu - Chemical Society Reviews, 2024 - pubs.rsc.org
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …

Construction of a two-dimensional artificial antioxidase for nanocatalytic rheumatoid arthritis treatment

B Yang, H Yao, J Yang, C Chen, J Shi - Nature Communications, 2022 - nature.com
Constructing nanomaterials mimicking the coordination environments of natural enzymes
may achieve biomimetic catalysis. Here we construct a two-dimensional (2D) metal-organic …