Structures and magnetic anisotropies of two seven-coordinate Co (ii)–nitrate complexes showing slow magnetic relaxation

W Lv, L Chen, XT Chen, H Yan, Z Wang… - New Journal of …, 2023 - pubs.rsc.org
Two seven-coordinate Co (II)-nitrate complexes,[Co (tmpdc)(NO3) 2](1) and [Co
(tmpdt)(NO3) 2]· CH3CN (2)(tmpdc= N, N, N′, N′-tetramethyl-2, 6-pyridinedicarboxamide …

Slow magnetic relaxation in mononuclear octa-coordinate Fe (II) and Co (II) complexes from a Bpybox ligand

RX Li, HY Sun, HC Liang, C Yi, NT Yao, YS Meng… - Dalton …, 2022 - pubs.rsc.org
Two 3d transition metal mononuclear complexes,[(FeL2)(ClO4) 2] 2· CH3CN (1) and
(CoL2)(ClO4) 2· 2CH3CN (2), have been prepared from a rigid tetradentate bpybox (L= 6 …

Slow Magnetic Relaxation in a Mononuclear 8‐Coordinate Fe (II) Compound Bearing the Phenanthroline‐Amide Ligand

JY Li, YL Huang, TC Li, Y Li, LX Wang… - Zeitschrift für …, 2023 - Wiley Online Library
A mononuclear 8‐coordinate Fe (II) compound,[FeII (L1) 2](CF3SO3) 2 (1), was prepared
from the reaction of a neutral tetradentate ligand (L1= N2, N9‐dibutyl‐1, 10‐phenanthroline …

Reciprocating thermal behaviour in a series of 7-coordinate Mn (ii) and Co (ii) complexes

LS Zhang, XX Jin, LX Wang, LL Liu, RY Qi… - Journal of Materials …, 2024 - pubs.rsc.org
Solvothermal reactions of tetradentate ligands, H2L1–H2L3, with hydrated Mn (ClO4) 2 and
hydrated Co (NO3) 2 afforded the mononuclear neutral compounds [MnII (L1)(H2O) 3] …

Synthesis, crystal structures, luminescence and magnetic properties of isostructural Ln (III) complexes based on a tetradentate ligand

YL Huang, J Xiang, LX Wang, Y Li, BB Yang… - Inorganic Chemistry …, 2023 - Elsevier
The hydrothermal reactions of a tetradentate ligand t Bu 2 L with hydrated Ln III (NO 3) 3
afforded three isostructural mononuclear Ln (III) compounds (NH 4)[Ln III (L) 2 (H 2 O)](Ln …

A pentagonal bipyramidal Co (II) single-ion magnet based on an asymmetric tetradentate ligand with easy plane anisotropy

XC Huang, W Yong, S Moorthy, ZY Su, JJ Kong… - Polyhedron, 2023 - Elsevier
High-coordinate 3d single-ion magnets (SIMs) especially with pentagonal bipyramidal
geometry as an emerging class of representative molecular magnets have received …

Slow magnetic relaxation in 8-coordinate Mn (ii) compounds

LX Wang, XF Wu, XX Jin, JY Li, BW Wang, JY Liu… - Dalton …, 2023 - pubs.rsc.org
The design and synthesis of high-spin Mn (II)-based single-molecule magnets (SMMs) have
not been well developed to a great extent, as compared with a large number of SMMs based …

Self-assembly of non-macrocyclic triangular Ni 3 Ln clusters

TN Dais, R Takano, T Ishida, PG Plieger - Dalton Transactions, 2022 - pubs.rsc.org
The synthesis and structural characterisation of four new heterometallic tetranuclear
complexes is reported. Three L3Ni3Ln type complexes, where Ln= La (C1), Eu (C2), and Gd …

Field‐Induced Slow Magnetization Relaxation of a Tetrahedral S= 2 FeIIS4‐Containing Complex

M Pissas, E Ferentinos, P Kyritsis, Y Sanakis - ChemPlusChem, 2024 - Wiley Online Library
In the work described herein, the spin relaxation properties of the mononuclear tetrahedral
S= 2 [Fe {(SPiPr2) 2N} 2] complex (1) were studied by employing static and dynamic …

Modulation of architectures and magnetic dynamics in pseudotetrahedral cobalt (II) complexes

Y Zhou, Y Li, J Xi, Y Qin, P Cen, YQ Zhang, Y Guo… - Dalton …, 2022 - pubs.rsc.org
Two β-Diketiminate cobalt (II) compounds of formula [LCo (μ-Cl)] 2· 2C6H14 (1) and
[LCoClPy]· 0.5 C7H8· 0.5 C6H14 (2)(L=[PhC-(PhCN-Dip) 2]−, Dip= 2, 6-iPr2C6H3) have …