Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

General design concept for single‐atom catalysts toward heterogeneous catalysis

W Guo, Z Wang, X Wang, Y Wu - Advanced Materials, 2021 - Wiley Online Library
As a new and popular material, single‐atom catalysts (SACs) exhibit excellent activity,
selectivity, and stability for numerous important reactions, and show great potential in …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Recent advances of single‐atom‐alloy for energy electrocatalysis

T Shen, S Wang, T Zhao, Y Hu… - Advanced Energy …, 2022 - Wiley Online Library
Abstract Single‐atom‐alloys (SAAs), as an emerging kind of materials, combine the
advantages of alloy and single‐atom catalysts. The full atomic utilization of active sites and …

Single-atom alloy catalysis

RT Hannagan, G Giannakakis… - Chemical …, 2020 - ACS Publications
Single-atom alloys (SAAs) play an increasingly significant role in the field of single-site
catalysis and are typically composed of catalytically active elements atomically dispersed in …

Single-atom alloy catalysts: structural analysis, electronic properties and catalytic activities

T Zhang, AG Walsh, J Yu, P Zhang - Chemical Society Reviews, 2021 - pubs.rsc.org
Monometallic catalysts, in particular those containing noble metals, are frequently used in
heterogeneous catalysis, but they are expensive, rare and the ability to tailor their structures …

Emerging Xene‐Based Single‐Atom Catalysts: Theory, Synthesis, and Catalytic Applications

M Wang, Y Hu, J Pu, Y Zi, W Huang - Advanced Materials, 2024 - Wiley Online Library
In recent years, the emergence of novel 2D monoelemental materials (Xenes), eg,
graphdiyne, borophene, phosphorene, antimonene, bismuthene, and stanene, has …

Heterogeneous single-atom catalysis

A Wang, J Li, T Zhang - Nature Reviews Chemistry, 2018 - nature.com
Single-atom catalysis has arguably become the most active new frontier in heterogeneous
catalysis. Aided by recent advances in practical synthetic methodologies, characterization …

[HTML][HTML] Magic of hydrogen spillover: Understanding and application

H Shen, H Li, Z Yang, C Li - Green Energy & Environment, 2022 - Elsevier
The hydrogen spillover effect (HSPE) plays an important role in heterogeneous catalysis
and hydrogen storage as an interfacial phenomenon, which facilitates the improvement of …