[HTML][HTML] Nonequilibrium thermodynamics in biochemical systems and its application

D Zhang, Q Ouyang - Entropy, 2021 - mdpi.com
Living systems are open systems, where the laws of nonequilibrium thermodynamics play
the important role. Therefore, studying living systems from a nonequilibrium thermodynamic …

Conservatively Perturbed Equilibrium (CPE) in chemical kinetics

GS Yablonsky, PD Branco, GB Marin… - Chemical Engineering …, 2019 - Elsevier
Abstract The phenomenon of “Conservatively Perturbed Equilibrium”(CPE) in chemical
kinetics is distinguished using a sequence of first-order reactions (linear mechanism) and …

Extended detailed balance for systems with irreversible reactions

AN Gorban, GS Yablonsky - Chemical Engineering Science, 2011 - Elsevier
The principle of detailed balance states that in equilibrium each elementary process is
equilibrated by its reverse process. For many real physico-chemical complex systems (eg …

Decoding complexity of chemical reactions

GS Yablonsky - Theoretical Foundations of Chemical Engineering, 2014 - Springer
Decoding Complexity of Chemical Reactions1 Page 1 ISSN 0040 5795, Theoretical
Foundations of Chemical Engineering, 2014, Vol. 48, No. 5, pp. 608–613. © Pleiades …

Thermodynamic time invariances for dual kinetic experiments: Nonlinear single reactions and more

D Constales, GS Yablonsky, GB Marin - Chemical engineering science, 2012 - Elsevier
For dual kinetic experiments, ie, experiments performed in batch or steady-state plug flow
reactors from reciprocal initial conditions, thermodynamic (space-) time invariances for all …

[HTML][HTML] New patterns in steady-state chemical kinetics: intersections, coincidences, map of events (two-step mechanism)

D Branco Pinto, G Yablonsky, GB Marin, D Constales - Entropy, 2015 - mdpi.com
New patterns of steady-state chemical kinetics for continuously stirred-tank reactors (CSTR)
have been found, ie, intersections, maxima and coincidences, for two-step mechanism A↔ …

Experimental confirmation of a new invariant for a non-linear chemical reaction

B Peng, GS Yablonsky, D Constales, GB Marin… - Chemical Engineering …, 2018 - Elsevier
The first non-Onsager thermodynamic invariant for a non-linear chemical system was found
experimentally in all domains using “the dual kinetic experiment” in a batch reactor in which …

[HTML][HTML] Bioelectromagnetic paradigm of cancer treatment—modulated electro-hyperthermia (mEHT)

O Szasz - Open Journal of Biophysics, 2019 - scirp.org
One of the most frequently applied bioelectromagnetic effects is the deep heating of the
living species with EMF energy. Despite its long history, hyperthermia is a rarely applied …

Joint kinetics: A new paradigm for chemical kinetics and chemical engineering

GS Yablonsky, D Constales, GB Marin - Current Opinion in Chemical …, 2020 - Elsevier
Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed.
Its main idea is performing a battery of kinetic experiments from special initial compositions …

New invariances for chemical reactions from Scaled Incremental Conversion (SIC)

PD Branco, GS Yablonsky, GB Marin… - Chemical Engineering …, 2018 - Elsevier
For the two-step chemical reaction A⇄ B⇄ C, invariant dependences of a new type have
been found. These invariants relate concentration dependences which are started from the …