Green synthesis of hypercrosslinked polymers for CO 2 capture and conversion: Recent advances, opportunities, and challenges

W Song, Y Tang, BR Moon, Q Liao, H Xu, Q Hou… - Green …, 2024 - pubs.rsc.org
The growing demand for fuel and industrial products has resulted in increased global CO2
emissions, which has accelerated global warming and made this an issue of widespread …

Boron‐Nitrogen Lewis Pairs in the Assembly of Supramolecular Macrocycles, Molecular Cages, Polymers, and 3D Materials

B Chen, F Jäkle - Angewandte Chemie, 2024 - Wiley Online Library
Covering an exceptionally wide range of bond strengths, the dynamic nature and facile
tunability of dative B− N bonds is highly attractive when it comes to the assembly of …

Porous frustrated Lewis pair catalysts: Advances and perspective

Y Zhang, PC Lan, K Martin, S Ma - Chem Catalysis, 2022 - cell.com
Summary Frustrated Lewis pairs (FLPs), well known for the ability to activate small
molecules via the concerted action of Lewis acid and Lewis base, have inspired an ever …

Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs

EA Latif, JD Hilgar, NA Romero - Journal of the American …, 2024 - ACS Publications
Polymeric materials bearing Frustrated Lewis Pair (FLP) functionality are promising
candidates for use as heterogeneous catalysts and adaptive materials, but synthetic access …

Cyclic ether triggers for polymeric frustrated Lewis pair gels

U Yolsal, TAR Horton, M Wang… - Journal of the American …, 2021 - ACS Publications
Sterically hindered Lewis acid and base centers are unable to form Lewis adducts, instead
forming frustrated Lewis pairs (FLPs), where latent reactivity can be utilized for the activation …

Ring Opening Copolymerization of Boron-Containing Anhydride with Epoxides as a Controlled Platform to Functional Polyesters

F Vidal, S Smith, CK Williams - Journal of the American Chemical …, 2023 - ACS Publications
Boron-functionalized polymers are used in opto-electronics, biology, and medicine. Methods
to produce boron-functionalized and degradable polyesters remain exceedingly rare but …

Controlling the aggregation and assembly of boron‐containing molecular and polymeric materials

D Shimoyama, F Jäkle - Aggregate, 2022 - Wiley Online Library
Boron‐containing molecules and polymers are attractive as powerful tunable Lewis acids for
small molecule activation and catalysis, as luminescent materials for organic electronic …

Polymeric frustrated Lewis pairs in CO 2/cyclic ether coupling catalysis

TAR Horton, M Wang, MP Shaver - Chemical Science, 2022 - pubs.rsc.org
Frustrated Lewis pairs (FLPs) are now ubiquitous as metal-free catalysts in an array of
different chemical transformations. In this paper we show that this reactivity can be …

Cross‐Linked Polymeric Micelles as Catalytic Nanoreactors

P Qu, M Kuepfert, E Ahmed, F Liu… - European Journal of …, 2021 - Wiley Online Library
Cross‐linked micelles have emerged as promising catalyst supports over the past two
decades due to their improved structural stability, chemical diversity in multiple domains …

“Activated Borane”: A Porous Borane Cluster Polymer as an Efficient Lewis Acid-Based Catalyst

M Lamac, B Urbán, M Horáček, D Buzek… - ACS …, 2023 - ACS Publications
Borane cluster-based porous covalent networks, named activated borane (ActB), were
prepared by cothermolysis of decaborane (14)(nido-B10H14) and selected hydrocarbons …