Emerging applications for living crystallization-driven self-assembly

L MacFarlane, C Zhao, J Cai, H Qiu, I Manners - Chemical Science, 2021 - pubs.rsc.org
The use of crystallization as a tool to control the self-assembly of polymeric and molecular
amphiphiles in solution is attracting growing attention for the creation of non-spherical …

RAFT-mediated polymerization-induced self-assembly (RAFT-PISA): current status and future directions

J Wan, B Fan, SH Thang - Chemical Science, 2022 - pubs.rsc.org
Polymerization-induced self-assembly (PISA) combines polymerization and self-assembly in
a single step with distinct efficiency that has set it apart from the conventional solution self …

Polymerization techniques in polymerization-induced self-assembly (PISA)

C Liu, CY Hong, CY Pan - Polymer Chemistry, 2020 - pubs.rsc.org
The development of controlled/“living” polymerization greatly stimulated the prosperity of the
fabrication and application of block copolymer nano-objects. Controlled/“living” …

50th Anniversary Perspective: Functional Nanoparticles from the Solution Self-Assembly of Block Copolymers

U Tritschler, S Pearce, J Gwyther, GR Whittell… - …, 2017 - ACS Publications
This Perspective outlines recent advances concerning the formation and potential uses of
block copolymer micelles, a class of soft-matter-based nanoparticles of growing importance …

Photoinitiated Polymerization‐Induced Self‐Assembly (Photo‐PISA): New Insights and Opportunities

J Yeow, C Boyer - Advanced Science, 2017 - Wiley Online Library
The polymerization‐induced self‐assembly (PISA) process is a useful synthetic tool for the
efficient synthesis of polymeric nanoparticles of different morphologies. Recently, studies on …

Mechanochemical unzipping of insulating polyladderene to semiconducting polyacetylene

Z Chen, JAM Mercer, X Zhu, JAH Romaniuk, R Pfattner… - Science, 2017 - science.org
Biological systems sense and respond to mechanical stimuli in a complex manner. In an
effort to develop synthetic materials that transduce mechanical force into multifold changes …

Principles and characteristics of polymerization-induced self-assembly with various polymerization techniques

EJ Cornel, J Jiang, S Chen, J Du - CCS Chemistry, 2021 - chinesechemsoc.org
A chemical reaction that drives a physical polymer self-assembly process, namely,
polymerization-induced self-assembly (PISA), combines block copolymer synthesis and …

Multidimensional hierarchical self-assembly of amphiphilic cylindrical block comicelles

H Qiu, ZM Hudson, MA Winnik, I Manners - Science, 2015 - science.org
Self-assembly of molecular and block copolymer amphiphiles represents a well-established
route to micelles with a wide variety of shapes and gel-like phases. We demonstrate an …

Scalable preparation of alternating block copolymer particles with inverse bicontinuous mesophases

F Lv, Z An, P Wu - Nature Communications, 2019 - nature.com
Block copolymer particles with controlled morphologies are of great significance in
nanomaterials and nanotechnology. However, ordered inverse morphologies are difficult to …

Scalable and uniform 1D nanoparticles by synchronous polymerization, crystallization and self-assembly

CE Boott, J Gwyther, RL Harniman, DW Hayward… - Nature Chemistry, 2017 - nature.com
The preparation of well-defined nanoparticles based on soft matter, using solution-
processing techniques on a commercially viable scale, is a major challenge of widespread …