Gas permeation properties, physical aging, and its mitigation in high free volume glassy polymers

ZX Low, PM Budd, NB McKeown… - Chemical reviews, 2018 - ACS Publications
Hundreds of polymers have been evaluated as membrane materials for gas separations, but
fewer than 10 have made it into current commercial applications, mainly due to the effects of …

[HTML][HTML] Polymers of intrinsic microporosity for energy-intensive membrane-based gas separations

Y Wang, X Ma, BS Ghanem, F Alghunaimi, I Pinnau… - Materials Today …, 2018 - Elsevier
This review provides a new perspective on the role of the state-of-the-art polymers of
intrinsic microporosity (PIMs) in key energy-intensive membrane-based gas separations …

Advances in organic microporous membranes for CO 2 separation

Y Wang, H Jiang, Z Guo, H Ma, S Wang… - Energy & …, 2023 - pubs.rsc.org
Carbon emission has become a worldwide concern with global warming and concurrent
climate changes. Carbon capture using membrane-based technology offers an effective way …

An efficient polymer molecular sieve for membrane gas separations

M Carta, R Malpass-Evans, M Croad, Y Rogan… - Science, 2013 - science.org
Microporous polymers of extreme rigidity are required for gas-separation membranes that
combine high permeability with selectivity. We report a shape-persistent ladder polymer …

Highly efficient and reversible iodine capture in hexaphenylbenzene-based conjugated microporous polymers

Y Liao, J Weber, BM Mills, Z Ren, CFJ Faul - Macromolecules, 2016 - ACS Publications
The effective and safe capture and storage of radioactive iodine (129I or 131I) is of
significant importance during nuclear waste storage and nuclear energy generation. Here …

Hexaphenylbenzene‐based deep blue‐emissive metallacages as donors for light‐harvesting systems

H Liu, Z Zhang, C Mu, L Ma, H Yuan… - Angewandte Chemie …, 2022 - Wiley Online Library
We herein report the preparation of a series of hexaphenylbenzene (HPB)‐based deep blue‐
emissive metallacages via multicomponent coordination‐driven self‐assembly. These …

Advances in high permeability polymeric membrane materials for CO 2 separations

N Du, HB Park, MM Dal-Cin, MD Guiver - Energy & Environmental …, 2012 - pubs.rsc.org
Global CO2 emissions have increased steadily in tandem with the use of fossil fuels. A
paradigm shift is needed in developing new ways by which energy is supplied and utilized …

[PDF][PDF] A spirobifluorene‐based polymer of intrinsic microporosity with improved performance for gas separation

CG Bezzu, M Carta, A Tonkins, JC Jansen… - Advanced …, 2012 - academia.edu
Highly energy-efficient separation of gases can be achieved using polymer membranes as
they do not require thermal regeneration, a phase change or active moving parts in their …

[HTML][HTML] Polymeric membranes on base of PolyMethyl methacrylate for air separation: a review

E Kianfar, V Cao - Journal of Materials Research and Technology, 2021 - Elsevier
Widespread applications of O 2 and N 2 especially in the oil, gas, and petrochemical
industries have put air separation process into the center of attention among researchers …

Next generation polymers of intrinsic microporosity with tunable moieties for ultrahigh permeation and precise molecular CO2 separation

AA Shamsabadi, M Rezakazemi, F Seidi… - Progress in Energy and …, 2021 - Elsevier
Polymers of intrinsic microporosity (PIMs) with high free volumes have been synthesized by
incorporating contorted rigid moieties into polymers backbones. Despite their many …