Nature's blueprint provides the fundamental principles for expanding the use of abundant
metals in catalysis; however, mimicking both the structure and function of copper enzymes …

Conspectus Metalloenzymes, which are proteins containing earth-abundant transition-metal
ions as cofactors in the active site, generate various metal–oxygen intermediates via …

Perchlorate (ClO4–) is a groundwater pollutant that is challenging to remediate. We report a
strategy to use Fe (II) tris (2-pyridylmethyl) amine (TPA) complexes featuring appended …

C− H activation represents an interesting alternative to conventional cross‐coupling
methods, avoiding the requirement of additional steps to introduce activating groups …

A high-valent manganese (IV)-hydroxo porphyrin π-cation radical complex,[Mn
(IV)(OH)(Porp+•)(X)]+, was synthesized and characterized spectroscopically. The Mn …

A series of mononuclear manganese (III)–hydroxo and− aqua complexes,[MnIII
(TBDAP)(OH) 2]+(1),[MnIII (TBDAP)(OH)(OH2)] 2+(2) and [MnIII (TBDAP)(OH2) 2] 3+(3) …

The hyporheic zone is a hotspot for biogeochemical cycling where interactions with mineral
metals preserve the release and biodegradation of organic matter (OM). A small fraction of …

Iron‐nitrenoid complexes can activate C− H bonds and, thus, potentially directly transform
C− H into C− N bonds. Low‐coordination complexes are the main reported systems; …

This paper presents the synthesis and characterization of a series of novel monomeric aqua‐
ligated iron (III) complexes,[FeIII (L5R)(OH2)] 2+(R= OMe, H, Cl, NO2), supported by an …

A possibility of using metal complexes with redox-active ligands in organic electrosynthesis
is demonstrated on the basis of literature data analysis. Unlike homogeneous catalysis …