Efficient deoxygenation methodologies catalyzed by oxo-molybdenum and oxo-rhenium complexes

SCA Sousa, AC Fernandes - Coordination Chemistry Reviews, 2015 - Elsevier
The deoxygenation of organic compounds is a fundamental process in both chemistry and
biology and the development of new efficient methodologies for the synthesis of …

Cis-dioxomolybdenum (VI) complex bearing tridentate ONO isonicotinoyl hydrazone Schiff base: synthesis, characterization, crystal structure, and catalytic activity …

H Kargar, M Fallah-Mehrjardi, M Ashfaq… - Journal of Molecular …, 2023 - Elsevier
A cis-dioxomolybdenum Schiff base complex, MoO 2 (L)(CH 3 OH), has been synthesized
by reacting MoO 2 (acac) 2 with isonicotinic acid hydrazide in refluxed methanol. The …

Synthetically important ring opening reactions by alkoxybenzenes and alkoxynaphthalenes

R Talukdar - RSC advances, 2020 - pubs.rsc.org
Alkoxybenzenes and alkoxynaphthalenes, as nucleophiles, have drawn great attention from
organic chemists over the decades. Due to their high ring strain, those particular classes of …

Molybdenum-catalyzed conversion of diols and biomass-derived polyols to alkenes using isopropyl alcohol as reductant and solvent

JR Dethlefsen, D Lupp, A Teshome, LB Nielsen… - ACS …, 2015 - ACS Publications
Chemical processes capable of reducing the high oxygen content of biomass-derived
polyols are in demand in order to produce renewable substitutes for chemicals of fossil …

Sustainable routes to alkenes: applications of homogeneous catalysis to the dehydration of alcohols to alkenes

DJ Ward, DJ Saccomando, G Walker… - Catalysis Science & …, 2023 - pubs.rsc.org
With the growing scientific and social awareness of environmental issues, there is an
increasing demand for renewable alkene feedstocks used to make the products we rely on …

Bis‐dioxomolybdenum (VI) oxalyldihydrazone complexes: Synthesis, characterization, DFT studies, catalytic epoxidation potential, molecular modeling and biological …

MSS Adam, MSM Ahmed, OM El‐Hady… - Applied …, 2020 - Wiley Online Library
Two cis‐bis‐dioxomolybdenum oxalylsalicylidenedihydrazone complexes (MoO2L1 and
MoO2L2) were synthesized via the complexation of dioxomolybdenum (VI) acetylacetonate …

A Recyclable acidic ionic liquid gel catalyst for dehydration: Comparison with an analogous SILP catalyst

YM Wang, V Ulrich, GF Donnelly… - ACS Sustainable …, 2015 - ACS Publications
An acid-functionalized ionic liquid was entrapped within a silica gel to yield a recyclable
liquid phase catalyst for the dehydration of rac-1-phenyl ethanol. Hot filtration tests showed …

Discrete mononuclear and dinuclear compounds containing a MoO 2 2+ core and 4-aminobenzhydrazone ligands: Synthesis, structure and organic-solvent-free …

D Cvijanović, J Pisk, G Pavlović, D Šišak-Jung… - New journal of …, 2019 - pubs.rsc.org
Cyclic dinuclear molybdenum (vi) complexes [MoO2 (L1–3)] 2 (1, 2-α, 2-β and 3) were
synthesized through the use of coordination-driven self-assembly of a MoO22+ core and 4 …

Diverse mechanistic pathways in single-site heterogeneous catalysis: alcohol conversions mediated by a high-valent carbon-supported molybdenum-dioxo catalyst

J Li, A Das, Q Ma, MJ Bedzyk, Y Kratish, TJ Marks - ACS Catalysis, 2022 - ACS Publications
With the increase in the importance of renewable resources, chemical research is shifting
focus toward substituting petrochemicals with biomass-derived analogues and platform …

Racemization Pathway for MoO2(acac)2 Favored over Ray–Dutt, Bailar, and Conte–Hippler Twists

G Dhimba, A Muller, K Lammertsma - Inorganic Chemistry, 2022 - ACS Publications
Chiral cis-MoO2 (acac) 2 racemizes via four pathways that agree with and extend upon
Muetterties' topological analysis for dynamic MX2 (chel) 2 complexes. Textbook Ray–Dutt …