Seven membered heterocyclic Azepine and its derivatives have great pharmacological and
therapeutic implications. In this review, the literature of the last fifty years has been exploited …

A strategy for the NHC‐catalyzed asymmetric synthesis of spirobenzazepinones, spiro‐1, 2‐
diazepinones, and spiro‐1, 2‐oxazepinones has been developed via [3+ 4]‐cycloaddition …

An enantioselective dearomative 1, 3-dipolar cycloaddition of 2-nitrobenzothiophenes and
isatin-derived azomethine ylides with a bifunctional hydrogen-bonding thiourea catalyst was …

A chiral tertiary amine-catalyzed asymmetric γ-regioselective (4+ 3) annulation reaction of
isatin-derived Morita–Baylis–Hillman carbonates and 1-azadienes was developed …

A series of five and six member rings N-substituted guanine have been synthesized. The
amine group has been protected first using phthalic anhydride. The nitrogen atoms have …

A novel and efficient strategy for the synthesis of a series of structurally interesting
benzazepine derivatives via an N-heterocyclic carbene-catalyzed regioselective …

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The application of plain cycloalkanes and heterocyclic derivatives in the synthesis of
valuable natural products and pharmacologically active intermediates has increased …

A silver-catalyzed oxidative intermolecular [3+ 2]/[5+ 2] annulation of N-arylpropiolamides
with 4-vinyl acids for producing fused 2 H-benzo [b] azepin-2-ones is described. This radical …

The visible-light-induced atom-economical synthesis of furan-fused dihydroazepine
derivatives under transition-metal and photocatalyst-free conditions is presented. This …