Crystallization assisted self-assembly of semicrystalline block copolymers

WN He, JT Xu - Progress in Polymer Science, 2012 - Elsevier
The self-assembly of block copolymers (BCPs) in the presence of crystallization as the
second driving force is reviewed, for BCPs in the bulk, thin films, single crystals and micelles …

Self‐Assembly of Copolymers Containing Crystallizable Blocks: Strategies and Applications

B Shi, D Shen, W Li, G Wang - Macromolecular Rapid …, 2022 - Wiley Online Library
The self‐assembly of copolymers containing crystallizable blocks in solution has received
increasing attention in the past few years. Various strategies including crystallization‐driven …

50th Anniversary Perspective: Polymer Crystals and Crystallization: Personal Journeys in a Challenging Research Field

B Lotz, T Miyoshi, SZD Cheng - Macromolecules, 2017 - ACS Publications
Analyzing and understanding the structure and morphology of crystalline polymers has been
and remains to be a major challenge. Some of the issues have resisted analyses for …

Block copolymer crystalsomes with an ultrathin shell to extend blood circulation time

H Qi, H Zhou, Q Tang, JY Lee, Z Fan, S Kim… - Nature …, 2018 - nature.com
In water, amphiphilic block copolymers (BCPs) can self-assemble into various micelle
structures depicting curved liquid/liquid interface. Crystallization, which is incommensurate …

Shape-shifting peptide nanomaterials: surface asymmetry enables pH-dependent formation and interconversion of collagen tubes and sheets

AD Merg, G Touponse, E Genderen… - Journal of the …, 2020 - ACS Publications
The fabrication of dynamic, transformable biomaterials that respond to environmental cues
represents a significant step forward in the development of synthetic materials that rival their …

A comprehensive review on polymer single crystals—From fundamental concepts to applications

S Agbolaghi, S Abbaspoor, F Abbasi - Progress in Polymer Science, 2018 - Elsevier
Polymer single crystals and correlated crystalline structures are reviewed by emphasizing
the last 10–20 years of research on fundamental concepts, single crystal engineering, and …

Crystallization-driven co-assembly of micrometric polymer hybrid single crystals and nanometric crystalline micelles

B Fan, RY Wang, XY Wang, JT Xu, BY Du… - Macromolecules, 2017 - ACS Publications
In the present work, crystallization-driven coassembly of micrometric polymer single crystals
and nanometric block copolymer micelles was achieved. The hybrid single crystals are first …

Hydrogen-bonding-mediated fragmentation and reversible self-assembly of crystalline micelles of block copolymer

JX Yang, B Fan, JH Li, JT Xu, BY Du, ZQ Fan - Macromolecules, 2016 - ACS Publications
Two hydrogen (H)-bond donors, phenol and l-threonine, were added into the aqueous
solutions containing crystalline micelles of a poly (ε-caprolactone)-b-poly (ethylene …

Corona liquid crystalline order helps to form single crystals when self-assembly takes place in the crystalline/liquid crystalline block copolymers

Z Tong, Y Li, H Xu, H Chen, W Yu, W Zhuo… - ACS Macro …, 2016 - ACS Publications
Crystalline/ionic liquid crystalline block copolymers (BCPs) with various compositions have
been successfully prepared by sequential reactions. The effect of corona liquid crystalline …

Breaking translational symmetry via polymer chain overcrowding in molecular bottlebrush crystallization

H Qi, X Liu, DM Henn, S Mei, MC Staub, B Zhao… - Nature …, 2020 - nature.com
One of the fundamental laws in crystallization is translational symmetry, which accounts for
the profound shapes observed in natural mineral crystals and snowflakes. Herein, we report …