Metal sites in zeolites: synthesis, characterization, and catalysis

Q Zhang, S Gao, J Yu - Chemical reviews, 2022 - ACS Publications
Zeolites with ordered microporous systems, distinct framework topologies, good spatial
nanoconfinement effects, and superior (hydro) thermal stability are an ideal scaffold for …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Emerging applications of zeolites in catalysis, separation and host–guest assembly

Y Li, J Yu - Nature Reviews Materials, 2021 - nature.com
Zeolites are a family of microporous crystalline materials, which, since the 1940s, have had
an indispensable role in the chemical industry as catalysts, adsorbents and ion exchangers …

Single-atom catalysts based on the metal–oxide interaction

R Lang, X Du, Y Huang, X Jiang, Q Zhang… - Chemical …, 2020 - ACS Publications
Metal atoms dispersed on the oxide supports constitute a large category of single-atom
catalysts. In this review, oxide supported single-atom catalysts are discussed about their …

Single-atom (iron-based) catalysts: synthesis and applications

B Singh, MB Gawande, AD Kute, RS Varma… - Chemical …, 2021 - ACS Publications
Supported single-metal atom catalysts (SACs) are constituted of isolated active metal
centers, which are heterogenized on inert supports such as graphene, porous carbon, and …

Maximizing noble metal utilization in solid catalysts by control of nanoparticle location

K Cheng, LCJ Smulders, LI van der Wal, J Oenema… - Science, 2022 - science.org
Maximizing the utilization of noble metals is crucial for applications such as catalysis. We
found that the minimum loading of platinum for optimal performance in the hydroconversion …

Advances in catalytic applications of zeolite‐supported metal catalysts

Q Sun, N Wang, J Yu - Advanced Materials, 2021 - Wiley Online Library
Zeolites possessing large specific surface areas, ordered micropores, and adjustable
acidity/basicity have emerged as ideal supports to immobilize metal species with small sizes …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Confining isolated atoms and clusters in crystalline porous materials for catalysis

L Liu, A Corma - Nature Reviews Materials, 2021 - nature.com
Abstract Structure–reactivity relationships for nanoparticle-based catalysts have been
greatly influenced by the study of catalytic materials with either supported isolated metal …

A theory/experience description of support effects in carbon-supported catalysts

IC Gerber, P Serp - Chemical Reviews, 2019 - ACS Publications
The support plays an important role for supported metal catalysts by positioning itself as a
macromolecular ligand, which conditions the nature of the active site and contributes …