Homogeneous gold catalysis has experienced extraordinary development since the dawn of
this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the …

Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …

Often stoichiometric amounts of gold find use in materials science; occasionally gold is even
used as a support. This review discusses the contributions of gold catalysis, both …

Organosilicon compounds act as a nucleophile upon activation by an appropriate base and
behave in a manner similar to main-group organometallic reagents. In the last decades …

For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …

The reluctance of gold to achieve oxidative addition reaction is considered as an intrinsic
limitation for the development of gold-catalyzed cross-coupling reactions with simple and …

Gold redox chemistry holds the promise of unique reactivities and selectivities that are
different to other transition metals. Recent studies have utilized strain release, ligand design …

Under visible‐light irradiation, the gold‐catalyzed intermolecular difunctionalization of
alkynes with aryl diazonium salts in methanol affords a variety of α‐aryl ketones in moderate …

The construction of C–C and C–X (X= hetero atom) bonds is the core aspect for the
assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling …

Conspectus Since the advent of metal-catalyzed cross-coupling technology more than 40
years ago, the field has grown to be ever-increasingly enabling, yet the employed coupling …