Homogeneous gold-catalyzed oxidation reactions
Homogeneous gold catalysis has experienced extraordinary development since the dawn of
this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the …
this millennium. Oxidative gold catalysis is a vibrant and fertile subfield and has over the …
Recent advances in gold (III) chemistry: structure, bonding, reactivity, and role in homogeneous catalysis
L Rocchigiani, M Bochmann - Chemical Reviews, 2020 - ACS Publications
Over the past decade the organometallic chemistry of gold (III) has seen remarkable
advances. This includes the synthesis of the first examples of several compound classes that …
advances. This includes the synthesis of the first examples of several compound classes that …
Homogeneous and heterogeneous gold catalysis for materials science
CM Hendrich, K Sekine, T Koshikawa… - Chemical …, 2020 - ACS Publications
Often stoichiometric amounts of gold find use in materials science; occasionally gold is even
used as a support. This review discusses the contributions of gold catalysis, both …
used as a support. This review discusses the contributions of gold catalysis, both …
Recent advances in transition-metal-catalyzed synthetic transformations of organosilicon reagents
T Komiyama, Y Minami, T Hiyama - ACS Catalysis, 2017 - ACS Publications
Organosilicon compounds act as a nucleophile upon activation by an appropriate base and
behave in a manner similar to main-group organometallic reagents. In the last decades …
behave in a manner similar to main-group organometallic reagents. In the last decades …
Reactivity of gold complexes towards elementary organometallic reactions
M Joost, A Amgoune… - Angewandte Chemie …, 2015 - Wiley Online Library
For a while, the reactivity of gold complexes was largely dominated by their Lewis acid
behavior. In contrast to the other transition metals, the elementary steps of organometallic …
behavior. In contrast to the other transition metals, the elementary steps of organometallic …
Rational development of catalytic Au (I)/Au (III) arylation involving mild oxidative addition of aryl halides
A Zeineddine, L Estévez, S Mallet-Ladeira… - Nature …, 2017 - nature.com
The reluctance of gold to achieve oxidative addition reaction is considered as an intrinsic
limitation for the development of gold-catalyzed cross-coupling reactions with simple and …
limitation for the development of gold-catalyzed cross-coupling reactions with simple and …
Homogeneous gold redox chemistry: organometallics, catalysis, and beyond
Gold redox chemistry holds the promise of unique reactivities and selectivities that are
different to other transition metals. Recent studies have utilized strain release, ligand design …
different to other transition metals. Recent studies have utilized strain release, ligand design …
Photosensitizer‐free visible‐light‐mediated gold‐catalyzed 1, 2‐difunctionalization of alkynes
L Huang, M Rudolph, F Rominger… - Angewandte Chemie …, 2016 - Wiley Online Library
Under visible‐light irradiation, the gold‐catalyzed intermolecular difunctionalization of
alkynes with aryl diazonium salts in methanol affords a variety of α‐aryl ketones in moderate …
alkynes with aryl diazonium salts in methanol affords a variety of α‐aryl ketones in moderate …
Oxidant-free oxidative gold catalysis: the new paradigm in cross-coupling reactions
The construction of C–C and C–X (X= hetero atom) bonds is the core aspect for the
assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling …
assembly of molecules. In this regard, late transition-metal-catalyzed cross-coupling …
Organogermanes as orthogonal coupling partners in synthesis and catalysis
C Fricke, F Schoenebeck - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus Since the advent of metal-catalyzed cross-coupling technology more than 40
years ago, the field has grown to be ever-increasingly enabling, yet the employed coupling …
years ago, the field has grown to be ever-increasingly enabling, yet the employed coupling …