Visible‐light photocatalysis: does it make a difference in organic synthesis?
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …
organic synthesis. Photocatalytic variants have been reported for many important …
Modern transition-metal-catalyzed carbon–halogen bond formation
The high utility of halogenated organic compounds has prompted the development of a vast
number of transformations which install the carbon–halogen motif. Traditional routes to …
number of transformations which install the carbon–halogen motif. Traditional routes to …
Use of bromine and bromo-organic compounds in organic synthesis
I Saikia, AJ Borah, P Phukan - Chemical reviews, 2016 - ACS Publications
Bromination is one of the most important transformations in organic synthesis and can be
carried out using bromine and many other bromo compounds. Use of molecular bromine in …
carried out using bromine and many other bromo compounds. Use of molecular bromine in …
Enzymatic halogenation and dehalogenation reactions: pervasive and mechanistically diverse
Naturally produced halogenated compounds are ubiquitous across all domains of life where
they perform a multitude of biological functions and adopt a diversity of chemical structures …
they perform a multitude of biological functions and adopt a diversity of chemical structures …
Expanding the enzyme universe: accessing non‐natural reactions by mechanism‐guided directed evolution
High selectivity and exquisite control over the outcome of reactions entice chemists to use
biocatalysts in organic synthesis. However, many useful reactions are not accessible …
biocatalysts in organic synthesis. However, many useful reactions are not accessible …
Catalytic mechanisms of Fe (II)-and 2-oxoglutarate-dependent oxygenases
S Martinez, RP Hausinger - Journal of Biological Chemistry, 2015 - ASBMB
Mononuclear non-heme Fe (II)-and 2-oxoglutarate (2OG)-dependent oxygenases comprise
a large family of enzymes that utilize an Fe (IV)-oxo intermediate to initiate diverse oxidative …
a large family of enzymes that utilize an Fe (IV)-oxo intermediate to initiate diverse oxidative …
Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?
Abstract Die Photokatalyse mit sichtbarem Licht hat sich im letzten Jahrzehnt zu einer breit
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …
Modular difunctionalization of unactivated alkenes through bio-inspired radical ligand transfer catalysis
KJ Bian, D Nemoto Jr, SC Kao, Y He, Y Li… - Journal of the …, 2022 - ACS Publications
Development of visible light-mediated atom transfer radical addition of haloalkanes onto
unsaturated hydrocarbons has seen rapid growth in recent years. However, due to its radical …
unsaturated hydrocarbons has seen rapid growth in recent years. However, due to its radical …
General and modular route to (Halo) alkyl BCP-heteroaryls enabled by α-aminoalkyl radical-mediated halogen-atom transfer
Y Guo, J Zhu, Y Wang, Y Li, H Hu, P Zhang, J Xu… - ACS …, 2023 - ACS Publications
Synthesis of bicyclo [1.1. 1] pentane (BCP) heteroaryls continues to be a part of the most
important tasks in organic synthesis because they are a significant class of bioisosteres with …
important tasks in organic synthesis because they are a significant class of bioisosteres with …
Genomes to natural products prediction informatics for secondary metabolomes (PRISM)
MA Skinnider, CA Dejong, PN Rees… - Nucleic acids …, 2015 - academic.oup.com
Microbial natural products are an invaluable source of evolved bioactive small molecules
and pharmaceutical agents. Next-generation and metagenomic sequencing indicates …
and pharmaceutical agents. Next-generation and metagenomic sequencing indicates …