Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …
achieving a fundamental understanding on the nature of the active sites in bimetallic …
Ensemble effect for single-atom, small cluster and nanoparticle catalysts
A large family of heterogeneous catalytic reactions require active sites with more than one
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …
metal atom, that is, an ensemble of metal atoms. The ensemble requirement, which refers to …
Zeolite-encaged isolated platinum ions enable heterolytic dihydrogen activation and selective hydrogenations
Understanding the unique behaviors of atomically dispersed catalysts and the origin thereof
is a challenging topic. Herein, we demonstrate a facile strategy to encapsulate Ptδ+ species …
is a challenging topic. Herein, we demonstrate a facile strategy to encapsulate Ptδ+ species …
Striding the threshold of an atom era of organic synthesis by single-atom catalysis
In the history of synthesis, people applied heat, electricity, and other means to expand the
synthesis field, thus promoting the construction of the magnificent material world. However …
synthesis field, thus promoting the construction of the magnificent material world. However …
Confined Heterojunction in Hollow-Structured TiO2 and Its Directed Effect in Photodriven Seawater Splitting
ST Xiao, SM Wu, L Wu, Y Dong, JW Liu, LY Wang… - ACS …, 2023 - ACS Publications
The high salinity of seawater often strongly affects the activity and stability of photocatalysts
utilized for photodriven seawater splitting. The current investigation is focused on the …
utilized for photodriven seawater splitting. The current investigation is focused on the …
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates
Searching for sustainable polymers requires access to biomass-based monomers. In that
sense, glucose-derived cis, cis-muconic acid stands as a high-potential intermediate …
sense, glucose-derived cis, cis-muconic acid stands as a high-potential intermediate …
Confinement-Induced Indium Oxide Nanolayers Formed on Oxide Support for Enhanced CO2 Hydrogenation Reaction
J Wang, R Li, G Zhang, C Dong, Y Fan… - Journal of the …, 2024 - ACS Publications
An enclosed nanospace often shows a significant confinement effect on chemistry within its
inner cavity, while whether an open space can have this effect remains elusive. Here, we …
inner cavity, while whether an open space can have this effect remains elusive. Here, we …
Single-atom heterogeneous catalysts for sustainable organic synthesis
Single-atom heterogeneous catalysts (SACs) incorporating isolated metal centers on solid
supports demonstrate promise for improving the sustainability of commercial organic …
supports demonstrate promise for improving the sustainability of commercial organic …
Coupling reactions induced by ionic palladium species deposited onto porous support materials
Á Mastalir, Á Molnár - Coordination Chemistry Reviews, 2022 - Elsevier
This review summarizes recent results reported on the catalytic applications of ionic
palladium species deposited onto different types of porous supports, including MCM and …
palladium species deposited onto different types of porous supports, including MCM and …
Water-promoted oxidative coupling of aromatics with subnanometer palladium clusters confined in zeolites
A fundamental understanding of the active sites in working catalysts can guide the rational
design of new catalysts with improved performances. In this work, we have followed the …
design of new catalysts with improved performances. In this work, we have followed the …