Calixarenes, macrocycles with (almost) unlimited possibilities

V Böhmer - Angewandte Chemie International Edition in …, 1995 - Wiley Online Library
The condensation reaction between p‐tert‐butylphenol and formaldehyde leads in a single
step to good yields of cyclic oligomers in which, depending on the reaction conditions, either …

Novel Cavity Design Using Calix[n]arene Skeletons:  Toward Molecular Recognition and Metal Binding

A Ikeda, S Shinkai - Chemical reviews, 1997 - ACS Publications
Calixarenes are macrocyclic molecules, like crown ethers and cyclodextrins. 1-7
Calixarenes made up of phenol and methylene units have many conformational isomers …

Calixarenes-the third generation of supramolecules

S Shinkai - Tetrahedron, 1993 - Elsevier
TETRAHEDRONREPORTNUMBER340 Page 1 Tdmhedron Vol. 49, No. 40. pp. 8933-8968.1993
Printed in Great Britain 00404020/93 $6.00+.00 h8Un0” RCSS Ind …

Chemistry of thiacalixarenes

P Lhoták - European Journal of Organic Chemistry, 2004 - Wiley Online Library
Thiacalixarenes—new members of the calixarene family—are very promising molecules
with many potential applications in supramolecular chemistry. The presence of four sulfur …

Calixarene–Makrocyclen mit (fast) unbegrenzten Möglichkeiten

V Böhmer - Angewandte Chemie, 1995 - Wiley Online Library
Durch Kondensation von p‐tert‐Butylphenol mit Formaldehyd sind in einem Schritt in guten
Ausbeuten cyclische Oligomere erhältlich, in denen je nach Reaktionsbedingungen vier …

Nitrocalix [4] arenes as molecules for second-order nonlinear optics

E Kelderman, W Verboom… - … Edition in English, 1992 - research.utwente.nl
The frequency-doubling of 820 nm laser light is one of the properties of a series of nitrocalix-
[4] arenes making them suitable, in principle, for the construction of a blue laser. Derivative 1 …

1,3‐Alternate Calix[4]arenecrown‐5 Conformers: New Synthetic Ionophores with Better K+/Na+ Selectivity than Valinomycin

A Casnati, A Pochini, R Ungaro… - … A European Journal, 1996 - Wiley Online Library
Abstract New 25, 27‐dialkoxycalix‐[4] arenecrown‐5 conformers 8, 10, and 11 have been
synthesized and studied. The compounds 8a and 8b, fixed in 1, 3‐alternate structure, have …

Conformational characteristics of ethers and esters of p-tert-butylcalix [5] arene

DR Stewart, M Krawiec, RP Kashyap… - Journal of the …, 1995 - ACS Publications
As part of a program involving the chemistry of the calix [5] arenes, a variety of ethers and
esters of p-tertbutylcalix [5] arene (lb) have been synthesized and their conformational …

Tetra-O-alkylated calix [4] arenes in the 1, 3-alternate conformation

W Verboom, S Datta, Z Asfari, S Harkema… - The Journal of …, 1992 - ACS Publications
Calixarenes, which are phenol-formaldehyde cyclic oligomers, are receiving increasing
attention in the field of supramolecular chemistry. 1, 2 Calix [4] arenes (Chart I) can easily be …

Synthesis of monoalkylated calix [4] arenes via direct alkylation

LC Groenen, BHM Ruël, A Casnati, W Verboom… - Tetrahedron, 1991 - Elsevier
A new one-step procedure for the synthesis of monoalkylated calix [4] arenes is presented.
Reaction of calix [4] arene 1a or 1b with 1.2 equivalent of a weak base (K2CO3 in MeCN or …