Improving the Chemical Utilization Efficiency of Pd Hydrodechlorination Catalysts through Hydrogen-Spillover Empowered Synergy between Pd and TiNiN Support

W Wang, X Zhang, W Ran, C Ma, J Sun… - Environmental …, 2024 - ACS Publications
The sustainable and affordable environmental application of Pd catalysis needs further
improvement of Pd mass activity. Besides the well-recognized importance of physical …

(Primary Amido)-ene (amido) Ni (II) Catalysts Containing a P-Chirogenic Substituted Ferrocene Moiety for Highly Enantioselective Asymmetric Transfer Hydrogenation …

H Chen, W Zuo - Organometallics, 2024 - ACS Publications
Asymmetric transfer hydrogenation (ATH) of ketones is an efficient method for constructing
chiral alcohols that are widely used in synthesizing various fine chemicals. Currently, most of …

A Tribute to Ullmann's Work: Expanding Copper Coil Reactor Applications toward the Hydroxylation of Aryl Bromides

M Molins, J Fernandez-Garcia… - … Process Research & …, 2024 - ACS Publications
Copper coil flow reactors represent an economic, abundant, and durable platform for
conducting copper-catalyzed reactions. These have been used in the past for Ullmann-type …

Room Temperature Ni‐Catalyzed Ullmann Reaction of (Hetero) aryl/Vinyl Chlorides Enabled by Silylchloride‐Activated Mn Powders

M Xü, S Wu, G Zou - European Journal of Organic Chemistry, 2024 - Wiley Online Library
A room temperature Ni‐catalyzed Mn‐mediated homocoupling of (hetero) aryl and vinyl
chlorides using Mn powders pre‐activated by trimethylsilylchloride (TMSCl) in DMA is …

Easily Accessible and Solution-Stable Ni (0) Precatalysts for High-Throughput Experimentation

G Thomas, O Cruise, D Peel-Smith, NP Fernández… - 2024 - chemrxiv.org
We report the synthesis, characterization, and catalytic applications of N, N'-diaryl
diazabutadiene (DAB) Ni (0) complexes stabilized by alkene ligands. These complexes are …