Biomimetic Metal-Free Hydride Donor Catalysts for CO2 Reduction
S Ilic, JL Gesiorski, RB Weerasooriya… - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The catalytic reduction of carbon dioxide to fuels and value-added chemicals is
of significance for the development of carbon recycling technologies. One of the main …
of significance for the development of carbon recycling technologies. One of the main …
Triple para-Functionalized Cations and Neutral Radicals of Enantiopure Diaza[4]helicenes
B Fabri, T Funaioli, L Frédéric, C Elsner… - Journal of the …, 2024 - ACS Publications
Modulation of absorbance and emission is key for the design of chiral chromophores.
Accessing a series of compounds absorbing and emitting (circularly polarized) light over a …
Accessing a series of compounds absorbing and emitting (circularly polarized) light over a …
Robust dual optical sensor for pH and dissolved oxygen
As part of moving our optical pH and dissolved oxygen (DO) optical chemosensors toward
industrial applications, we decided to explore a many-sensors-in-one principle. It was tested …
industrial applications, we decided to explore a many-sensors-in-one principle. It was tested …
Kinetics of Hydride Transfer from Catalytic Metal-Free Hydride Donors to CO2
RB Weerasooriya, JL Gesiorski, A Alherz… - The Journal of …, 2021 - ACS Publications
Selective reduction of CO2 to formate represents an ongoing challenge in
photoelectrocatalysis. To provide mechanistic insights, we investigate the kinetics of hydride …
photoelectrocatalysis. To provide mechanistic insights, we investigate the kinetics of hydride …
Toward Metal-free Photocatalysis: Photochemical Regeneration of Organic Hydride Donors Using Phenazine-Based Photosensitizers
RB Weerasooriya, MC Drummer… - The Journal of …, 2022 - ACS Publications
Earth-abundant chromophores and catalysts are important molecular building blocks for
artificial photosynthesis applications. Our team previously reported that metal-free hydride …
artificial photosynthesis applications. Our team previously reported that metal-free hydride …
Chemo‐ and Regioselective Multiple C(sp2)−H Insertions of Malonate Metal Carbenes for Late‐Stage Functionalizations of Azahelicenes
Y Nikolova, B Fabri, P Moneva Lorente… - Angewandte Chemie …, 2022 - Wiley Online Library
Chiral quinacridines react up to four times, step‐by‐step, with α‐diazomalonates under RuII
and RhII catalysis. By selecting the catalyst,[CpRu (CH3CN) 3][PF6](Cp= cyclopentadienyl) …
and RhII catalysis. By selecting the catalyst,[CpRu (CH3CN) 3][PF6](Cp= cyclopentadienyl) …
Importance of proton-coupled electron transfer in cathodic regeneration of organic hydrides
Electrochemical regeneration of organic hydrides is often hindered by the rapid dimerization
of organic radicals produced as the first intermediates of these electrochemical …
of organic radicals produced as the first intermediates of these electrochemical …
Recent progress in photocatalytic NAD (P) H regeneration for photocatalytic-enzymatic-coupling system
W Lan, M Wang, H Dai, Q Yang - Frontiers of Chemical Science and …, 2024 - Springer
The enzymatic redox reactions in natural photosynthesis rely much on the participation of
cofactors, with reduced nicotinamide adenine dinucleotide/nicotinamide adenine …
cofactors, with reduced nicotinamide adenine dinucleotide/nicotinamide adenine …
Triple regioselective functionalization of cationic [4] helicenes via iridium‐catalyzed borylation and Suzuki cross‐coupling reactivity
L Frédéric, B Fabri, L Guénée, F Zinna… - … A European Journal, 2022 - Wiley Online Library
In essentially one‐pot, using Ir‐and Pd‐catalysis, tris (arene)‐functionalized cationic [4]
helicenes are synthesized with full regioselectivity and enantiospecificity starting from a …
helicenes are synthesized with full regioselectivity and enantiospecificity starting from a …
Exciton coherence length and dynamics in graphene quantum dot assemblies
Exciton size and dynamics were studied in assemblies of two well-defined graphene
quantum dots of varying size: hexabenzocoronene (HBC), where the aromatic core consists …
quantum dots of varying size: hexabenzocoronene (HBC), where the aromatic core consists …