Laboratory investigations of Titan haze formation: In situ measurement of gas and particle composition

SM Hörst, YH Yoon, MS Ugelow, AH Parker, R Li… - Icarus, 2018 - Elsevier
Prior to the arrival of the Cassini-Huygens spacecraft, aerosol production in Titan's
atmosphere was believed to begin in the stratosphere where chemical processes are …

CO2 infrared phonon modes in interstellar ice mixtures

IR Cooke, EC Fayolle, KI Öberg - The Astrophysical Journal, 2016 - iopscience.iop.org
ABSTRACT CO 2 ice is an important reservoir of carbon and oxygen in star-and planet-
forming regions. Together with water and CO, CO 2 sets the physical and chemical …

Nonnegligible generation of hydroxyl radicals from UVC photolysis of aqueous nitrous oxide

G Zhang, S Wei, B Wu, Z Chen… - Environmental science & …, 2018 - ACS Publications
Nitrous oxide (N2O) is widely used in radiation-chemistry and photochemistry as a
scavenger to convert a hydrated electron (e aq–) into a hydroxyl radical (· OH). However, few …

Optimization of a solar simulator for planetary-photochemical studies

E Es-sebbar, Y Bénilan, N Fray, H Cottin… - The Astrophysical …, 2015 - iopscience.iop.org
Low-temperature microwave-powered plasma based on hydrogen and hydrogen with noble
gas mixtures are widely used as a continuous vacuum ultraviolet (VUV) source in laboratory …

A NEW SOURCE OF CO2 IN THE UNIVERSE: A PHOTOACTIVATED ELEY–RIDEAL SURFACE REACTION ON WATER ICES

C Yuan, IR Cooke, JT Yates - The Astrophysical Journal Letters, 2014 - iopscience.iop.org
ABSTRACT CO 2 is one of the most abundant components of ices in the interstellar medium;
however, its formation mechanism has not been clearly identified. Here we report an …

Lyman-α photodesorption from CO2 (ice) at 75 K: Role of CO2 vibrational relaxation on desorption rate

C Yuan, JT Yates - The Journal of Chemical Physics, 2013 - pubs.aip.org
The photodesorption of CO 2 from CO 2 (ice) at 75 K when irradiated by Lyman-α light is
strongly mediated by vibrational relaxation of highly vibrationally excited molecules …

Variation in photon flux during extended photochemical aerosol experiments: Implications for atmospheric laboratory simulations

JA Sebree, JM Wayson, JR Lopez - Journal of Photochemistry and …, 2018 - Elsevier
In order to simulate the interaction of sunlight with planetary atmospheres, including Pluto,
Titan and the early Earth, many laboratory studies have used high-power broadband lamps …

Lyman-α driven molecule formation on SiO2 surfaces—connection to astrochemistry on dust grains in the interstellar medium

M Rajappan, C Yuan, JT Yates - The Journal of chemical physics, 2011 - pubs.aip.org
As a model for silicate dust grains in the interstellar medium, we have used high area
amorphous SiO 2 as a surface on which to carry out Lyman-α (10.2 eV) photodecomposition …

Isotope effect in the photochemical decomposition of CO2 (ice) by Lyman-α radiation

C Yuan, JT Yates - The Journal of Chemical Physics, 2013 - pubs.aip.org
The photochemical decomposition of CO 2 (ice) at 75 K by Lyman-α radiation (10.2 eV) has
been studied using transmission infrared spectroscopy. An isotope effect in the …

Experimental study of heterogeneous organic chemistry induced by far ultraviolet light: Implications for growth of organic aerosols by CH3 addition in the atmospheres …

P Hong, Y Sekine, T Sasamori, S Sugita - Icarus, 2018 - Elsevier
Formation of organic aerosols driven by photochemical reactions has been observed and
suggested in CH 4-containing atmospheres, including Titan and early Earth. However, the …