Does Larger Cavity‐Size Really Help Bigger Anions to Bind? A Scrutiny on Core‐Expanded Calix [4] pyrroles and Their Properties

M Giri, Y Dash, T Guchhait - ChemPlusChem, 2024 - Wiley Online Library
Calix [4] pyrroles are an important class of oligopyrrolic macrocycles and have found
applications in many diverse fields including anion recognition. To modulate the properties …

PVC membrane, coated-wire, and carbon-paste ion-selective electrodes for potentiometric determination of galantamine hydrobromide in physiological fluids

FM Abdel-Haleem, M Saad, A Barhoum… - Materials Science and …, 2018 - Elsevier
We report on highly-sensitive ion-selective electrodes (ISEs) for potentiometric determining
of galantamine hydrobromide (GB) in physiological fluids. Galantamine hydrobromide (GB) …

Design and characterization of electrochemical sensor for the determination of mercury (II) ion in real samples based upon a new schiff base derivative as an …

SS Alharthi, AM Fallatah, HM Al-Saidi - Sensors, 2021 - mdpi.com
The present paper provides a description of the design, characterization, and use of a Hg2+
selective electrode (Hg2+–SE) for the determination of Hg2+ at ultra-traces levels in a …

[HTML][HTML] Reconnoitering the dynamics-calix [4] pyrrole: A heights in research and technology

B Dhumale, KD Bhatt, N Patel, K Modi - Results in Chemistry, 2023 - Elsevier
Calix [4] pyrrole has potential applications as a molecular recognition receptor, sensor,
ditopic cation, and anion receptor. Other supramolecular receptors could be made using …

Effect of AgNPs internal solution on the sensing of mercury (II) by an ion-selective electrode based on a thiol coordination from cysteine as ionophore

A Elgamouz, I Shehadi, A Assal, A Bihi… - Journal of …, 2021 - Elsevier
The use of nanoparticles in the sensing of mercury from environmental and biological fluids
is limited to optical and colorimetric sensors. The present research investigates the use of …

Calix [4] based Hg (II) ion selective electrodes: A thermodynamic protocol to address the selectivity versus the hosting capacity paradigm in the selection of the carrier

AFD de Namor, S Alharthi, A El Gamouz… - Electrochimica …, 2018 - Elsevier
A new calix [4] arene derivative, L 1, and its interaction with cations has been structurally
and thermodynamically characterised. The thermodynamics of cation complexation of a calix …

Anion Complexation by an Azocalix[4]arene Derivative and the Scope of Its Fluoride Complex Salt to Capture CO2 from the Air

AF Danil de Namor, N Al Hakawati - Molecules, 2023 - mdpi.com
A newly synthesized upper rim azocalix [4] arene, namely 5, 11, 17, 23-tetra [(4-
ethylacetoxyphenyl)(azo)] calix [4] arene, CA-AZ has been fully characterized, and its …

Efficacious Removal of Flonicamid Insecticide from Water by GO@ functionalized Calix [4] pyrrole: Synergistic Effect in Adsorption

Raveena, Alka, N Gandhi, P Kumari - ChemistrySelect, 2023 - Wiley Online Library
The presence of a highly toxic pyridine carboxamide insecticide, namely flonicamid in water
bodies poses a serious risk to both the aquatic ecosystem and human health. Therefore, a …

Calix [4] arene urea derivatives: The pathway from fundamental studies to the selective removal of fluorides and phosphates from water

AFDD de Namor, W Abou Hamdan, O Webb… - Journal of hazardous …, 2019 - Elsevier
Wet processes of phosphoric acids produce untreated wastewater containing large amounts
of fluoride leading to serious environmental problems. This paper reports fundamental …

[HTML][HTML] An asymmetric N-rim partially substituted calix [4] pyrrole: Its affinity for Ag (I) and its destruction by Hg (II)

JK Chaaban, N Al Hakawati, B Howlin… - Arabian Journal of …, 2020 - Elsevier
A new partially substituted calix [4] pyrrole derivative obtained by the introduction of three
thioamide functionalities in the N-rim has been synthesised and fully characterised by 1 H …