Photoactive iron complexes: more sustainable, but still a challenge
On transition metals such as iron rests lots of hope to replace precious metal catalysts in the
field of photochemistry for a more sustainable future. Indeed, significant progress has been …
field of photochemistry for a more sustainable future. Indeed, significant progress has been …
Photophysics and photochemistry of iron carbene complexes for solar energy conversion and photocatalysis
Earth-abundant first row transition metal complexes are important for the development of
large-scale photocatalytic and solar energy conversion applications. Coordination …
large-scale photocatalytic and solar energy conversion applications. Coordination …
Intraligand excited states turn a ruthenium oligothiophene complex into a light-triggered Ubertoxin with anticancer effects in extreme hypoxia
Ru (II) complexes that undergo photosubstitution reactions from triplet metal-centered (3MC)
excited states are of interest in photochemotherapy (PCT) due to their potential to produce …
excited states are of interest in photochemotherapy (PCT) due to their potential to produce …
Photophysical Integrity of the Iron(III) Scorpionate Framework in Iron(III)–NHC Complexes with Long-Lived 2LMCT Excited States
Fe (III) complexes with N-heterocyclic carbene (NHC) ligands belong to the rare examples of
Earth-abundant transition metal complexes with long-lived luminescent charge-transfer …
Earth-abundant transition metal complexes with long-lived luminescent charge-transfer …
Panchromatic light harvesting and record power conversion efficiency for carboxylic/cyanoacrylic Fe (ii) NHC co-sensitized FeSSCs
A Reddy-Marri, E Marchini, VD Cabanes, R Argazzi… - Chemical …, 2023 - pubs.rsc.org
Fe (II) pyridyl-NHC sensitizers bearing thienylcyanoacrylic (ThCA) anchoring groups have
been designed and characterized with the aim of enhancing the metal to surface charge …
been designed and characterized with the aim of enhancing the metal to surface charge …
Beyond the First Coordination Sphere─ Manipulating the Excited-State Landscape in Iron (II) Chromophores with Protons
K Witas, SS Nair, T Maisuradze, L Zedler… - Journal of the …, 2024 - ACS Publications
Molecular transition metal chromophores play a central role in light harvesting and energy
conversion. Recently, earth-abundant transition-metal-based chromophores have begun to …
conversion. Recently, earth-abundant transition-metal-based chromophores have begun to …
A Tetracarbene Iron (II) Complex with a Long‐lived Triplet Metal‐to‐Ligand Charge Transfer State due to a Triplet‐Triplet Barrier
T Reuter, D Zorn, R Naumann, J Klett… - Angewandte Chemie …, 2024 - Wiley Online Library
Mixed N‐heterocyclic carbene (NHC)/pyridyl iron (II) complexes have attracted a great deal
of attention recently because of their potential as photocatalysts and light sensitizers made …
of attention recently because of their potential as photocatalysts and light sensitizers made …
Multifaceted Deactivation Dynamics of Fe(II) N-Heterocyclic Carbene Photosensitizers
Excited state dynamics of three iron (II) carbene complexes that serve as prototype Earth-
abundant photosensitizers were investigated by ultrafast optical spectroscopy. Significant …
abundant photosensitizers were investigated by ultrafast optical spectroscopy. Significant …
Ultrafast Spectroscopy of Fe (II) Complexes Designed for Solar‐Energy Conversion: Current Status and Open Questions
One major challenge of future sustainable photochemistry is to replace precious and rare
transition metals in applications such as energy conversion or electroluminescence by earth …
transition metals in applications such as energy conversion or electroluminescence by earth …
Iron-Sensitized Solar Cells (FeSSCs)
M Pastore, S Caramori, PC Gros - Accounts of Chemical Research, 2024 - ACS Publications
Conspectus The harvesting and conversion of solar energy have become a burning issue
for our modern societies seeking to move away from the exploitation of fossil fuels. In this …
for our modern societies seeking to move away from the exploitation of fossil fuels. In this …