Evolution, achievements, and perspectives of the TAP technique

J Pérez-Ramírez, EV Kondratenko - Catalysis Today, 2007 - Elsevier
This manuscript concisely reviews the significance of the temporal analysis of products
(TAP) technique in catalysis research from its introduction to the scientific community in the …

Temporal analysis of products (TAP)—recent advances in technology for kinetic analysis of multi-component catalysts

JT Gleaves, G Yablonsky, X Zheng, R Fushimi… - Journal of Molecular …, 2010 - Elsevier
This paper presents an overview of the evolution, advancements, and capabilities of the
temporal analysis of products (TAP) reactor system as a unique catalyst characterization …

[HTML][HTML] Forty years of temporal analysis of products

K Morgan, N Maguire, R Fushimi, JT Gleaves… - Catalysis Science & …, 2017 - pubs.rsc.org
A detailed understanding of reaction mechanisms and kinetics is required in order to
develop and optimize catalysts and catalytic processes. While steady-state investigations …

[HTML][HTML] Interrogating site dependent kinetics over SiO2-supported Pt nanoparticles

TS Kim, CR O'Connor, C Reece - Nature Communications, 2024 - nature.com
A detailed knowledge of reaction kinetics is key to the development of new more efficient
heterogeneous catalytic processes. However, the ability to resolve site dependent kinetics …

Crossing the great divide between single-crystal reactivity and actual catalyst selectivity with pressure transients

C Reece, EA Redekop, S Karakalos, CM Friend… - Nature Catalysis, 2018 - nature.com
The quantitative prediction of catalyst selectivity is essential to the design of efficient catalytic
processes and requires a detailed knowledge of the reaction mechanism and rate constants …

[HTML][HTML] Simplifying the Temporal Analysis of Products reactor

L Brandão, EA High, TS Kim, C Reece - Chemical Engineering Journal, 2023 - Elsevier
Abstract The Temporal Analysis of Products (TAP) experiment provides an unparalleled
level of kinetic insight into heterogenous catalytic materials, but due to the complex and …

A well-defined supported Pt nanoparticle catalyst for heterogeneous catalytic surface science

TS Kim, CR O'Connor, SL Le, C Reece - Journal of Materials Chemistry …, 2024 - pubs.rsc.org
Our ability to rationalise the activity of heterogeneous catalytic materials relies on a precise
understanding of both the structure and composition of the catalyst under reaction conditions …

Temporal analysis of products: basic principles, applications, and theory

GS Yablonsky, M Olea, GB Marin - Journal of Catalysis, 2003 - Elsevier
This paper discusses a temporal analysis of products approach, which can be considered as
an advanced kinetic strategy at the boundary between traditional applied kinetics and …

Site-specific scaling relations observed during methanol-to-olefin conversion over ZSM-5 catalysts

T Omojola - Chemical Engineering Science, 2022 - Elsevier
The conversion of methanol over ZSM-5 catalysts was studied using step response and
temperature-programmed desorption and surface reaction analyses in a temporal analysis …

“State defining” experiment in chemical kinetics—primary characterization of catalyst activity in a TAP experiment

SO Shekhtman, GS Yablonsky, JT Gleaves… - Chemical engineering …, 2003 - Elsevier
This paper presents a new strategy,“state-by-state transient screening”, for kinetic
characterization of states of a multicomponent catalyst as applied to TAP pulse-response …