Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

RAFT polymerization to form stimuli-responsive polymers

G Moad - Polymer Chemistry, 2017 - pubs.rsc.org
Stimuli-responsive polymers adapt to their surrounding environment. These polymers are
capable of responding to a variety of external stimuli, which include optical, electrical …

RAFT agent design and synthesis

DJ Keddie, G Moad, E Rizzardo, SH Thang - Macromolecules, 2012 - ACS Publications
This Perspective reviews the design and synthesis of RAFT agents. First, we briefly detail the
basic design features that should be considered when selecting a RAFT agent or macro …

Bioapplications of RAFT polymerization

C Boyer, V Bulmus, TP Davis, V Ladmiral, J Liu… - Chemical …, 2009 - ACS Publications
A living radical polymerization (LRP) is a free radical polymerization that aims at displaying
living character,(ie, does not terminate or transfer and is able to continue polymerization …

Porous polymer particles—A comprehensive guide to synthesis, characterization, functionalization and applications

MT Gokmen, FE Du Prez - Progress in polymer science, 2012 - Elsevier
This review is written to fulfill the need of a comprehensive guide for the manufacture of
porous polymer particles. The synthesis section discusses and for the first time compares …

Complex polymer architectures via RAFT polymerization: From fundamental process to extending the scope using click chemistry and nature's building blocks

A Gregory, MH Stenzel - Progress in Polymer Science, 2012 - Elsevier
Reversible addition fragmentation chain transfer (RAFT) polymerization has made a huge
impact in macromolecular design. The first block copolymers were described early on …

Living radical polymerization by the RAFT process–a second update

G Moad, E Rizzardo, SH Thang - Australian journal of chemistry, 2009 - CSIRO Publishing
This paper provides a second update to the review of reversible deactivation radical
polymerization achieved with thiocarbonylthio compounds (ZC (= S) SR) by a mechanism of …

Engineering live cell surfaces with functional polymers via cytocompatible controlled radical polymerization

J Niu, DJ Lunn, A Pusuluri, JI Yoo, MA O'Malley… - Nature Chemistry, 2017 - nature.com
The capability to graft synthetic polymers onto the surfaces of live cells offers the potential to
manipulate and control their phenotype and underlying cellular processes. Conventional …

Macromolecular engineering through click chemistry and other efficient transformations

BS Sumerlin, AP Vogt - Macromolecules, 2010 - ACS Publications
Precision synthesis of advanced polymeric materials requires efficient, robust, and facile
chemical reactions. Paradoxically, the synthesis of increasingly intricate macromolecular …

Bioorthogonal reactions utilizing nitrones as versatile dipoles in cycloaddition reactions

DA Bilodeau, KD Margison, M Serhan… - Chemical …, 2021 - ACS Publications
Bioorthogonal chemical reactions have emerged as convenient and rapid methods for
incorporating unnatural functionality into living systems. Different prototype reactions have …