Polymers without petrochemicals: sustainable routes to conventional monomers

G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …

Sustainable developments in polyolefin chemistry: Progress, challenges, and outlook

XY Wang, Y Gao, Y Tang - Progress in Polymer Science, 2023 - Elsevier
Polyolefins are the largest-scale synthetic plastics and play a key role in modern society.
Their production consumes huge amounts of fossil-derived monomer feedstocks, which …

Multifunctional catalysts for ring-opening copolymerizations

CAL Lidston, SM Severson, BA Abel, GW Coates - ACS catalysis, 2022 - ACS Publications
The ring-opening copolymerization (ROCOP) of epoxides with CO2 or cyclic anhydrides is a
versatile route toward synthesizing a wide range of polycarbonate and polyester …

Spiro-salen catalysts enable the chemical synthesis of stereoregular polyhydroxyalkanoates

HY Huang, W Xiong, YT Huang, K Li, Z Cai, JB Zhu - Nature Catalysis, 2023 - nature.com
Although bacterial stereoregular polyhydroxyalkanoates have attracted broad interest as
sustainable materials, it remains a long-standing challenge to chemically synthesize …

Biorenewable and circular polydiketoenamine plastics

J Demarteau, B Cousineau, Z Wang, B Bose… - Nature …, 2023 - nature.com
Amid growing concerns over the human health and environmental impacts of plastic waste,
the most promising solution would be to build a circular plastics economy where …

Designing a circular carbon and plastics economy for a sustainable future

F Vidal, ER van der Marel, RWF Kerr, C McElroy… - Nature, 2024 - nature.com
The linear production and consumption of plastics today is unsustainable. It creates large
amounts of unnecessary and mismanaged waste, pollution and carbon dioxide emissions …

Polyolefins vitrimers: design principles and applications

M Ahmadi, A Hanifpour, S Ghiassinejad… - Chemistry of …, 2022 - ACS Publications
Less than 10% of plastics are recycled worldwide, among which polyolefins, which form two-
thirds of all produced polymers, are the most discarded ones. This stems from the nonpolar …

Closed-loop chemical recycling of cross-linked polymeric materials based on reversible amidation chemistry

B Qin, S Liu, Z Huang, L Zeng, JF Xu… - Nature Communications, 2022 - nature.com
Closed-loop chemical recycling provides a solution to the end-of-use problem of synthetic
polymers. However, it remains a major challenge to design dynamic bonds, capable of …

A recyclable polyester library from reversible alternating copolymerization of aldehyde and cyclic anhydride

X Zhang, W Guo, C Zhang, X Zhang - Nature Communications, 2023 - nature.com
Our society is pursuing chemically recyclable polymers to accelerate the green revolution in
plastics. Here, we develop a recyclable polyester library from the alternating …

Dual recycling of depolymerization catalyst and biodegradable polyester that markedly outperforms polyolefins

XL Li, RW Clarke, HY An, RR Gowda… - Angewandte …, 2023 - Wiley Online Library
Chemically recyclable, circular polymers continue to attract increasing attention, but
rendering both catalysts for depolymerization and high‐performance polymers recyclable is …