[图书][B] Isotope effects in chemistry and biology

A Kohen, HH Limbach - 2005 - taylorfrancis.com
The field of isotope effects has expanded exponentially in the last decade, and researchers
are finding isotopes increasingly useful in their studies. Bringing literature on the subject up …

A spectroscopic overview of intramolecular hydrogen bonds of NH… O, S, N type

PE Hansen - Molecules, 2021 - mdpi.com
Intramolecular NH… O, S, N interactions in non-tautomeric systems are reviewed in a broad
range of compounds covering a variety of NH donors and hydrogen bond acceptors. 1H …

Studies based on deuterium isotope effect on 13C chemical shifts

T Dziembowska, PE Hansen, Z Rozwadowski - Progress in Nuclear …, 2004 - Elsevier
Contents 1. Introduction............................................................................. 2 2. Theoretical
background and theoretical calculations................................................ 2 2.1 …

Multi-catalysis reactions: direct organocatalytic sequential one-pot synthesis of highly functionalized cyclopenta [b] chromen-1-ones

DB Ramachary, YV Reddy, M Kishor - Organic & Biomolecular …, 2008 - pubs.rsc.org
We have developed a new technology called multi-catalysis for the sequential one-pot
synthesis of highly functionalized heterocycles. A practical and novel multi-component …

Theoretical, structural, vibrational, NMR, and thermal evidence of the inter-versus intramolecular hydrogen bonding in oxamides and thiooxamides

HO Desseyn, SP Perlepes, K Clou… - The Journal of …, 2004 - ACS Publications
This contribution describes the study of hydrogen bonding in secondary oxamides,
monothiooxamides, and dithiooxamides by ab initio calculations, X-ray diffractions, NMR …

Temperature coefficient of NH chemical shifts of thioamides and amides in relation to structure

JG Sośnicki, PE Hansen - Journal of molecular structure, 2004 - Elsevier
NH chemical shift temperature coefficients have been measured in a large series of N-
substituted-3-piperidinethiopropionamides in which the N⋯ N distances are short but of …

Strong intramolecular hydrogen bonds and steric effects involving C═ S groups: An NMR and computational study

RS Elias, BA Saeed, FS Kamounah… - Magnetic …, 2020 - Wiley Online Library
A number of 5‐acyl rhodanines and thiorhodanines with bulky acyl groups (pivaloyl and
adamantoyl), not previously available, have been synthesized. The compounds are shown …

Synthesis of the N-allylthioamide derivatives of cyclic oxo-and dioxo-acids and their cyclization to the derivatives of 4, 5-dihydrothiazole

A Wesołowska, TS Jagodziński, JG Sośnicki… - Polish Journal of …, 2001 - infona.pl
The title N-allylthioamides (1a-f) were synthesized in the reaction of allyl isothiocyanate with
enamines (1a-c) and 1, 3-diketones (1d-f), respectively, carried out in an acetonitrile solution …

Long-Range Deuterium Isotope Effects on 13C Chemical Shifts of Intramolecularly Hydrogen-Bonded N-Substituted 3-(Cycloamine)thiopropionamides or Amides:  A …

JG Sośnicki, M Langaard… - The Journal of Organic …, 2007 - ACS Publications
A series of intramolecularly hydrogen-bonded N-substituted 3-(piperidine, morpholine, N-
methylpiperazine) thiopropionamides and some corresponding amides have been studied …

Isotope effects on chemical shifts as a tool in the study of tautomeric equilibria

PE Hansen - Tautomerism: Methods and Theories, 2013 - Wiley Online Library
The chapter introduces isotope effects on chemical shifts. It also contains a description of
potential energy surfaces in relation to tautomeric equilibria focusing on zero point energies …