Living systems use chemical fuels to transiently assemble functional structures. As a step
toward constructing abiotic mimics of such structures, we herein describe dissipative …

A supramolecular chiral hydrogen-bonded tetrameric aggregate possessing a large cavity
and tetraarylporphyrin substituents was assembled using alternating 4H-and 2H-bonds …

Biophysical characterization of protein–protein interactions involving disordered proteins is
challenging. A common simplification is to measure the thermodynamics and kinetics of …

We demonstrate a new approach to chemosensors suited for analysis of phosphate
mixtures. Here, a combination of a cross-reactive receptor and an environmentally sensitive …

Molecules are dynamic entities, and understanding intra-and inter-molecular reactions and
changes in conformation is one of the most fascinating, important and complex subjects in …

In biological systems, biomolecules achieve sophisticated functions based on both
thermodynamic control and kinetic control. In contrast, in artificial supramolecular systems …

Fluorinated piperidines find wide applications, most notably in the development of novel
therapies and agrochemicals. Cyclization of alkenyl N-tosylamides promoted by BF3 …

Biomorphic supramolecular assemblies formed through the collaboration of rigid and
flexible elements, akin to bones and ligaments, play a crucial role in constructing advanced …

The precise positioning of functional groups about the inner space of abiotic hosts is a
challenging task and of interest for developing more effective receptors and catalysts akin to …

We describe the preparation, dynamic, assembly characteristics of vase‐shaped basket 13−
along with its ability to form an inclusion complex with anticancer drug mitoxantrone in …