Utilization of methylarenes as versatile building blocks in organic synthesis

R Vanjari, KN Singh - Chemical Society Reviews, 2015 - pubs.rsc.org
The development of practical and efficient methods for C–C and C–X bond formation has
attracted a great deal of current attention with the advent of C–H functionalization reactions …

[HTML][HTML] Cross-dehydrogenative coupling for the intermolecular C–O bond formation

IB Krylov, VA Vil, AO Terent'ev - Beilstein journal of organic …, 2015 - beilstein-journals.org
The present review summarizes primary publications on the cross-dehydrogenative C–O
coupling, with special emphasis on the studies published after 2000. The starting …

Copper-Catalyzed Esterification of Alkylbenzenes with Cyclic Ethers and Cycloalkanes via C(sp3)–H Activation Following Cross-Dehydrogenative Coupling

SK Rout, S Guin, W Ali, A Gogoi, BK Patel - Organic letters, 2014 - ACS Publications
A copper-catalyzed cross-dehydrogenative coupling strategy has been developed for the
synthesis of two classes of esters from simple solvents. The reaction of methylarenes with …

Iron-Catalyzed Cross-Dehydrogenative Coupling Esterification of Unactive C(sp3)–H Bonds with Carboxylic Acids for the Synthesis of α-Acyloxy Ethers

J Zhao, H Fang, W Zhou, J Han… - The Journal of Organic …, 2014 - ACS Publications
An iron-catalyzed oxidative esterification reaction between unactivated C (sp3)–H bonds
from symmetric and asymmetric ethers and carboxylic acids using di-tert-butyl peroxide …

Copper‐Catalyzed Direct C‐3 Benzylation of Quinoxalin‐2(1H)‐ones with Methylarenes under Microwave Irradiation

L Hu, J Yuan, J Fu, T Zhang, L Gao… - European Journal of …, 2018 - Wiley Online Library
A novel and efficient approach to the C (sp2)–H/C (sp3)–H oxidative coupling of quinoxalin‐
2 (1H)‐ones with methylarenes by using CuI as catalyst is reported. Various substrates were …

Metal-free oxidative C (sp 3)–H bond functionalization of alkanes and alkylation-initiated radical 1, 2-aryl migration in α, α-diaryl allylic alcohols

J Zhao, H Fang, R Song, J Zhou, J Han… - Chemical …, 2015 - pubs.rsc.org
An oxidative C (sp3)–H bond functionalization of alkanes and alkylation-initiated radical 1, 2-
aryl migration in α, α-diaryl allylic alcohols using di-tert-butyl peroxide (DTBP) as the oxidant …

Synthesis of esters via sp 3 C–H functionalisation

G Majji, SK Rout, S Rajamanickam, S Guin… - Organic & Biomolecular …, 2016 - pubs.rsc.org
Oxidative C–O bond formation via sp3 C–H functionalisation represents an attractive
approach for the synthesis of esters. This review focuses on the recent advances of sp3 C–H …

Regiospecific Benzoylation of Electron-Deficient N-Heterocycles with Methylbenzenes via a Minisci-Type Reaction

W Ali, A Behera, S Guin, BK Patel - The Journal of Organic …, 2015 - ACS Publications
A regioselective cross-dehydrogenative coupling between electron-deficient N-heterocycles
(isoquinoline, quinolines, and quinoxalines) and methylbenzenes leading to regiospecific C …

C 1-Benzyl and benzoyl isoquinoline synthesis through direct oxidative cross-dehydrogenative coupling with methyl arenes

M Wan, H Lou, L Liu - Chemical Communications, 2015 - pubs.rsc.org
An oxidative cross-dehydrogenative coupling (CDC) of isoquinolines with methyl arenes has
been developed, allowing for the facile synthesis of a broad range of structurally diverse C1 …

Bu4NI Catalyzed C–N Bond Formation via Cross-Dehydrogenative Coupling of Aryl Ethers (Csp3–H) and Tetrazoles (N–H)

S Rajamanickam, G Majji, SK Santra, BK Patel - Organic letters, 2015 - ACS Publications
Intermolecular C–N bond formations via cross-dehydrogenative coupling (CDC) of aryl
ethers and tetrazoles have been developed under a metal-free condition. In the presence of …